A series of novel indium complexes derived from aromatic carboxylic acids: Hydrothermal syntheses, crystal structures, supramolecular networks and fluorescent properties

Xin Ming Wang; Rui Qing Fan; Liang Sheng Qiang; Ping Wang; Yu Lin Yang; Yu Lei Wang

doi:10.1016/j.inoche.2015.03.016

A series of novel indium complexes derived from aromatic carboxylic acids: Hydrothermal syntheses, crystal structures, supramolecular networks and fluorescent properties

Xin Ming Wang
, Rui Qing Fan^*
, Liang Sheng Qiang
, Ping Wang
, Yu Lin Yang
, Yu Lei Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Abstract Five new compounds with mixed-ligand formulated as (H₄bptc)(phen) (1), [In(phen)₂Cl₂](H₄bptc)(NO₃)(H₂O) (2), [In(Hbptc)(phen)(H₂O)]₂ (3), In(2,6-pydc)(phen)(H₂O)Cl (4), and {[In(2,6-pydc)(Ox)_0.5(H₂O)₂](H₂O)}₂ (5) have been synthesized under hydrothermal conditions. Compounds 1-5 display white, green and blue fluorescence at 298 K in the solid state, respectively. It is shown that 1 assumes solvent-dependent photoluminescence. By contrast, the different polarities of solvents do not alter the luminescence position of 3 and 5. The thermogravimetric curves show that binuclear compounds 3 and 5 have excellent thermal stability, whose structures are stable up to 190 and 272 C, respectively.

Original language	English
Article number	5913
Pages (from-to)	73-76
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	55
DOIs	https://doi.org/10.1016/j.inoche.2015.03.016
State	Published - May 2015

Keywords

Fluorescence
Hydrothermal condition
Solvent-dependent photoluminescence
Thermal stability

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10.1016/j.inoche.2015.03.016

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@article{5b6d7edea541493a80df10ff3a397919,

title = "A series of novel indium complexes derived from aromatic carboxylic acids: Hydrothermal syntheses, crystal structures, supramolecular networks and fluorescent properties",

abstract = "Abstract Five new compounds with mixed-ligand formulated as (H4bptc)(phen) (1), [In(phen)2Cl2](H4bptc)(NO3)(H2O) (2), [In(Hbptc)(phen)(H2O)]2 (3), In(2,6-pydc)(phen)(H2O)Cl (4), and \{[In(2,6-pydc)(Ox)0.5(H2O)2](H2O)\}2 (5) have been synthesized under hydrothermal conditions. Compounds 1-5 display white, green and blue fluorescence at 298 K in the solid state, respectively. It is shown that 1 assumes solvent-dependent photoluminescence. By contrast, the different polarities of solvents do not alter the luminescence position of 3 and 5. The thermogravimetric curves show that binuclear compounds 3 and 5 have excellent thermal stability, whose structures are stable up to 190 and 272 C, respectively.",

keywords = "Fluorescence, Hydrothermal condition, Solvent-dependent photoluminescence, Thermal stability",

author = "Wang, \{Xin Ming\} and Fan, \{Rui Qing\} and Qiang, \{Liang Sheng\} and Ping Wang and Yang, \{Yu Lin\} and Wang, \{Yu Lei\}",

note = "Publisher Copyright: {\textcopyright} 2015 Published by Elsevier B.V.",

year = "2015",

month = may,

doi = "10.1016/j.inoche.2015.03.016",

language = "英语",

volume = "55",

pages = "73--76",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

A series of novel indium complexes derived from aromatic carboxylic acids: Hydrothermal syntheses, crystal structures, supramolecular networks and fluorescent properties. / Wang, Xin Ming; Fan, Rui Qing; Qiang, Liang Sheng et al.
In: Inorganic Chemistry Communications, Vol. 55, 5913, 05.2015, p. 73-76.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A series of novel indium complexes derived from aromatic carboxylic acids

T2 - Hydrothermal syntheses, crystal structures, supramolecular networks and fluorescent properties

AU - Wang, Xin Ming

AU - Fan, Rui Qing

AU - Qiang, Liang Sheng

AU - Wang, Ping

AU - Yang, Yu Lin

AU - Wang, Yu Lei

PY - 2015/5

Y1 - 2015/5

N2 - Abstract Five new compounds with mixed-ligand formulated as (H4bptc)(phen) (1), [In(phen)2Cl2](H4bptc)(NO3)(H2O) (2), [In(Hbptc)(phen)(H2O)]2 (3), In(2,6-pydc)(phen)(H2O)Cl (4), and {[In(2,6-pydc)(Ox)0.5(H2O)2](H2O)}2 (5) have been synthesized under hydrothermal conditions. Compounds 1-5 display white, green and blue fluorescence at 298 K in the solid state, respectively. It is shown that 1 assumes solvent-dependent photoluminescence. By contrast, the different polarities of solvents do not alter the luminescence position of 3 and 5. The thermogravimetric curves show that binuclear compounds 3 and 5 have excellent thermal stability, whose structures are stable up to 190 and 272 C, respectively.

AB - Abstract Five new compounds with mixed-ligand formulated as (H4bptc)(phen) (1), [In(phen)2Cl2](H4bptc)(NO3)(H2O) (2), [In(Hbptc)(phen)(H2O)]2 (3), In(2,6-pydc)(phen)(H2O)Cl (4), and {[In(2,6-pydc)(Ox)0.5(H2O)2](H2O)}2 (5) have been synthesized under hydrothermal conditions. Compounds 1-5 display white, green and blue fluorescence at 298 K in the solid state, respectively. It is shown that 1 assumes solvent-dependent photoluminescence. By contrast, the different polarities of solvents do not alter the luminescence position of 3 and 5. The thermogravimetric curves show that binuclear compounds 3 and 5 have excellent thermal stability, whose structures are stable up to 190 and 272 C, respectively.

KW - Fluorescence

KW - Hydrothermal condition

KW - Solvent-dependent photoluminescence

KW - Thermal stability

UR - https://www.scopus.com/pages/publications/84924991455

U2 - 10.1016/j.inoche.2015.03.016

DO - 10.1016/j.inoche.2015.03.016

M3 - 文章

AN - SCOPUS:84924991455

SN - 1387-7003

VL - 55

SP - 73

EP - 76

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 5913

ER -

A series of novel indium complexes derived from aromatic carboxylic acids: Hydrothermal syntheses, crystal structures, supramolecular networks and fluorescent properties

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