A Series of Compounds Based on [P2W18O62]6- and Transition Metal Mixed Organic Ligand Complexes with High Catalytic Properties for Styrene Epoxidation

Ying Lü; Xiao Zhang; Xiao Bing Cui; Ji Qing Xu

doi:10.1021/acs.inorgchem.8b01705

A Series of Compounds Based on [P₂W₁₈O₆₂]^6- and Transition Metal Mixed Organic Ligand Complexes with High Catalytic Properties for Styrene Epoxidation

Ying Lü
, Xiao Zhang
, Xiao Bing Cui^*
, Ji Qing Xu

^*Corresponding author for this work

College of Chemistry
Tonghua Normal University
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Seven compounds based on [P₂W₁₈O₆₂]^6- ({P₂W₁₈}) were successfully prepared and carefully characterized. [HC₅H₅N][Cu(2,2′-bpy)₂]₂[HP₂W₁₈O₆₂]·2H₂O (bpy = bipyridine) (1) is constructed from {P₂W₁₈} bridged by [Cu(2,2′-bpy)₂]²⁺. [HC₅H₅N][Zn(2,2′-bpy)₂]₂[HP₂W₁₈O₆₂]·4H₂O (1a) is isostructural and isomorphous with compound 1. [Cu₄(2,2′-bpy)₃(nic)₃(OH)₂(H₂O)][H₃P₂W₁₈O₆₂]·0.5H₂O (nic = nicotinic acid) (2) is formed by {P₂W₁₈} and tetracopper transition metal mixed organic ligand complexes (TMMCs). [Cu₂(2,2′-bpy)₂(C₂O₄)]₃[P₂W₁₈O₆₂]·3H₂O (3) is made up of {P₂W₁₈} and bicopper TMMCs, [Cu₆(2,2′-bpy)₆(OH)₆][P₂W₁₈O₆₂]·2H₂O (4) is built up from {P₂W₁₈}, and hexacopper complexes of 2,2′-bpy and hydroxyls. [Cu(2,2′-bpy)(hnic)_0.5][Cu₃(2,2′-bpy)₃(hnic)₂(H₂O)₂][H₃P₂W₁₈O₆₂] (hnic = hydroxyl nicotinic acid) (5a) contains two different TMMCs. In addition, compound 5a is the first example of a compound that contains Cu-π interactions. [Cu₂(2,2′-bpy)₂(hnic)][H₄P₂W₁₈O₆₂]·xH₂O (x ≈ 50) (5b) is based on {P₂W₁₈} and [Cu₂(2,2′-bpy)₂(hnic)]²⁺. We discuss the mechanisms for the formations of these compounds. All the catalytic performances of the compounds for styrene epoxidation to styrene oxide are high.

Original language	English
Pages (from-to)	11123-11134
Number of pages	12
Journal	Inorganic Chemistry
Volume	57
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.8b01705
State	Published - 4 Sep 2018
Externally published	Yes

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@article{fd3f7c40cd744f8683d086be589e20ae,

title = "A Series of Compounds Based on [P2W18O62]6- and Transition Metal Mixed Organic Ligand Complexes with High Catalytic Properties for Styrene Epoxidation",

abstract = "Seven compounds based on [P2W18O62]6- (\{P2W18\}) were successfully prepared and carefully characterized. [HC5H5N][Cu(2,2′-bpy)2]2[HP2W18O62]·2H2O (bpy = bipyridine) (1) is constructed from \{P2W18\} bridged by [Cu(2,2′-bpy)2]2+. [HC5H5N][Zn(2,2′-bpy)2]2[HP2W18O62]·4H2O (1a) is isostructural and isomorphous with compound 1. [Cu4(2,2′-bpy)3(nic)3(OH)2(H2O)][H3P2W18O62]·0.5H2O (nic = nicotinic acid) (2) is formed by \{P2W18\} and tetracopper transition metal mixed organic ligand complexes (TMMCs). [Cu2(2,2′-bpy)2(C2O4)]3[P2W18O62]·3H2O (3) is made up of \{P2W18\} and bicopper TMMCs, [Cu6(2,2′-bpy)6(OH)6][P2W18O62]·2H2O (4) is built up from \{P2W18\}, and hexacopper complexes of 2,2′-bpy and hydroxyls. [Cu(2,2′-bpy)(hnic)0.5][Cu3(2,2′-bpy)3(hnic)2(H2O)2][H3P2W18O62] (hnic = hydroxyl nicotinic acid) (5a) contains two different TMMCs. In addition, compound 5a is the first example of a compound that contains Cu-π interactions. [Cu2(2,2′-bpy)2(hnic)][H4P2W18O62]·xH2O (x ≈ 50) (5b) is based on \{P2W18\} and [Cu2(2,2′-bpy)2(hnic)]2+. We discuss the mechanisms for the formations of these compounds. All the catalytic performances of the compounds for styrene epoxidation to styrene oxide are high.",

author = "Ying L{\"u} and Xiao Zhang and Cui, \{Xiao Bing\} and Xu, \{Ji Qing\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = sep,

day = "4",

doi = "10.1021/acs.inorgchem.8b01705",

language = "英语",

volume = "57",

pages = "11123--11134",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "17",

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T1 - A Series of Compounds Based on [P2W18O62]6- and Transition Metal Mixed Organic Ligand Complexes with High Catalytic Properties for Styrene Epoxidation

AU - Lü, Ying

AU - Zhang, Xiao

AU - Cui, Xiao Bing

AU - Xu, Ji Qing

PY - 2018/9/4

Y1 - 2018/9/4

N2 - Seven compounds based on [P2W18O62]6- ({P2W18}) were successfully prepared and carefully characterized. [HC5H5N][Cu(2,2′-bpy)2]2[HP2W18O62]·2H2O (bpy = bipyridine) (1) is constructed from {P2W18} bridged by [Cu(2,2′-bpy)2]2+. [HC5H5N][Zn(2,2′-bpy)2]2[HP2W18O62]·4H2O (1a) is isostructural and isomorphous with compound 1. [Cu4(2,2′-bpy)3(nic)3(OH)2(H2O)][H3P2W18O62]·0.5H2O (nic = nicotinic acid) (2) is formed by {P2W18} and tetracopper transition metal mixed organic ligand complexes (TMMCs). [Cu2(2,2′-bpy)2(C2O4)]3[P2W18O62]·3H2O (3) is made up of {P2W18} and bicopper TMMCs, [Cu6(2,2′-bpy)6(OH)6][P2W18O62]·2H2O (4) is built up from {P2W18}, and hexacopper complexes of 2,2′-bpy and hydroxyls. [Cu(2,2′-bpy)(hnic)0.5][Cu3(2,2′-bpy)3(hnic)2(H2O)2][H3P2W18O62] (hnic = hydroxyl nicotinic acid) (5a) contains two different TMMCs. In addition, compound 5a is the first example of a compound that contains Cu-π interactions. [Cu2(2,2′-bpy)2(hnic)][H4P2W18O62]·xH2O (x ≈ 50) (5b) is based on {P2W18} and [Cu2(2,2′-bpy)2(hnic)]2+. We discuss the mechanisms for the formations of these compounds. All the catalytic performances of the compounds for styrene epoxidation to styrene oxide are high.

AB - Seven compounds based on [P2W18O62]6- ({P2W18}) were successfully prepared and carefully characterized. [HC5H5N][Cu(2,2′-bpy)2]2[HP2W18O62]·2H2O (bpy = bipyridine) (1) is constructed from {P2W18} bridged by [Cu(2,2′-bpy)2]2+. [HC5H5N][Zn(2,2′-bpy)2]2[HP2W18O62]·4H2O (1a) is isostructural and isomorphous with compound 1. [Cu4(2,2′-bpy)3(nic)3(OH)2(H2O)][H3P2W18O62]·0.5H2O (nic = nicotinic acid) (2) is formed by {P2W18} and tetracopper transition metal mixed organic ligand complexes (TMMCs). [Cu2(2,2′-bpy)2(C2O4)]3[P2W18O62]·3H2O (3) is made up of {P2W18} and bicopper TMMCs, [Cu6(2,2′-bpy)6(OH)6][P2W18O62]·2H2O (4) is built up from {P2W18}, and hexacopper complexes of 2,2′-bpy and hydroxyls. [Cu(2,2′-bpy)(hnic)0.5][Cu3(2,2′-bpy)3(hnic)2(H2O)2][H3P2W18O62] (hnic = hydroxyl nicotinic acid) (5a) contains two different TMMCs. In addition, compound 5a is the first example of a compound that contains Cu-π interactions. [Cu2(2,2′-bpy)2(hnic)][H4P2W18O62]·xH2O (x ≈ 50) (5b) is based on {P2W18} and [Cu2(2,2′-bpy)2(hnic)]2+. We discuss the mechanisms for the formations of these compounds. All the catalytic performances of the compounds for styrene epoxidation to styrene oxide are high.

UR - https://www.scopus.com/pages/publications/85053030956

U2 - 10.1021/acs.inorgchem.8b01705

DO - 10.1021/acs.inorgchem.8b01705

M3 - 文章

C2 - 30113167

AN - SCOPUS:85053030956

SN - 0020-1669

VL - 57

SP - 11123

EP - 11134

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 17

ER -

A Series of Compounds Based on [P₂W₁₈O₆₂]^6- and Transition Metal Mixed Organic Ligand Complexes with High Catalytic Properties for Styrene Epoxidation

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