A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

Xikui Fang; Paul Kögerler; Manfred Speldrich; Helmut Schilder; Marshall Luban

doi:10.1039/c1cc15520b

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

Xikui Fang^*
, Paul Kögerler
, Manfred Speldrich
, Helmut Schilder
, Marshall Luban

^*Corresponding author for this work

Ames Laboratory
RWTH Aachen University

Research output: Contribution to journal › Article › peer-review

91 Scopus citations

Abstract

Ligand modification transforms a polyoxometalate-anchored cubane-type [Mn^III₃Mn^IVO₄] core into a centrosymmetric [Mn^III₆Mn^IVO₈] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn₄O₄] cubane-based single-molecule magnets.

Original language	English
Pages (from-to)	1218-1220
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	9
DOIs	https://doi.org/10.1039/c1cc15520b
State	Published - 9 Jan 2012
Externally published	Yes

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title = "A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state",

abstract = "Ligand modification transforms a polyoxometalate-anchored cubane-type [MnIII3MnIVO4] core into a centrosymmetric [MnIII6MnIVO8] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn4O4] cubane-based single-molecule magnets.",

author = "Xikui Fang and Paul K{\"o}gerler and Manfred Speldrich and Helmut Schilder and Marshall Luban",

year = "2012",

month = jan,

day = "9",

doi = "10.1039/c1cc15520b",

language = "英语",

volume = "48",

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journal = "Chemical Communications",

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T1 - A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

AU - Fang, Xikui

AU - Kögerler, Paul

AU - Speldrich, Manfred

AU - Schilder, Helmut

AU - Luban, Marshall

PY - 2012/1/9

Y1 - 2012/1/9

N2 - Ligand modification transforms a polyoxometalate-anchored cubane-type [MnIII3MnIVO4] core into a centrosymmetric [MnIII6MnIVO8] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn4O4] cubane-based single-molecule magnets.

AB - Ligand modification transforms a polyoxometalate-anchored cubane-type [MnIII3MnIVO4] core into a centrosymmetric [MnIII6MnIVO8] di-cubane cluster, and restores the slow magnetization relaxation characteristics typical for [Mn4O4] cubane-based single-molecule magnets.

UR - https://www.scopus.com/pages/publications/84855591596

U2 - 10.1039/c1cc15520b

DO - 10.1039/c1cc15520b

M3 - 文章

AN - SCOPUS:84855591596

SN - 1359-7345

VL - 48

SP - 1218

EP - 1220

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

A polyoxometalate-based single-molecule magnet with an S = 21/2 ground state

Abstract

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