A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanion [Ce(PW11O39)2]10- and sodium ion linker

Lihua Fan; Lin Xu; Guanggang Gao; Fengyan Li; Zhikui Li; Yunfeng Qiu

doi:10.1016/j.inoche.2006.08.006

A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanion [Ce(PW₁₁O₃₉)₂]^10- and sodium ion linker

Lihua Fan
, Lin Xu^*
, Guanggang Gao
, Fengyan Li
, Zhikui Li
, Yunfeng Qiu

^*Corresponding author for this work

Ministry of Education of the People's Republic of China

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

A novel sandwich-type lanthanide polyoxometalate (NH₄)₂[N(CH₃)₄]₆Na₂[Ce(PW₁₁O₃₉)₂] · 14H₂O (1) has been synthesized and characterized by cyclic voltammetry, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction result reveals that the sandwich-type polyanions are linked by sodium ions to form a structure of zigzag chains, and the chains are further connected into an extensive two-dimensional (2D) framework depending on hydrogen bond.

Original language	English
Pages (from-to)	1308-1311
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2006.08.006
State	Published - Dec 2006
Externally published	Yes

Keywords

Chain
Framework
Lanthanide
Polyoxometalate
Sandwich

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10.1016/j.inoche.2006.08.006

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title = "A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanion [Ce(PW11O39)2]10- and sodium ion linker",

abstract = "A novel sandwich-type lanthanide polyoxometalate (NH4)2[N(CH3)4]6Na2[Ce(PW11O39)2] · 14H2O (1) has been synthesized and characterized by cyclic voltammetry, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction result reveals that the sandwich-type polyanions are linked by sodium ions to form a structure of zigzag chains, and the chains are further connected into an extensive two-dimensional (2D) framework depending on hydrogen bond.",

keywords = "Chain, Framework, Lanthanide, Polyoxometalate, Sandwich",

author = "Lihua Fan and Lin Xu and Guanggang Gao and Fengyan Li and Zhikui Li and Yunfeng Qiu",

year = "2006",

month = dec,

doi = "10.1016/j.inoche.2006.08.006",

language = "英语",

volume = "9",

pages = "1308--1311",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "12",

}

TY - JOUR

T1 - A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanion [Ce(PW11O39)2]10- and sodium ion linker

AU - Fan, Lihua

AU - Xu, Lin

AU - Gao, Guanggang

AU - Li, Fengyan

AU - Li, Zhikui

AU - Qiu, Yunfeng

PY - 2006/12

Y1 - 2006/12

N2 - A novel sandwich-type lanthanide polyoxometalate (NH4)2[N(CH3)4]6Na2[Ce(PW11O39)2] · 14H2O (1) has been synthesized and characterized by cyclic voltammetry, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction result reveals that the sandwich-type polyanions are linked by sodium ions to form a structure of zigzag chains, and the chains are further connected into an extensive two-dimensional (2D) framework depending on hydrogen bond.

AB - A novel sandwich-type lanthanide polyoxometalate (NH4)2[N(CH3)4]6Na2[Ce(PW11O39)2] · 14H2O (1) has been synthesized and characterized by cyclic voltammetry, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction result reveals that the sandwich-type polyanions are linked by sodium ions to form a structure of zigzag chains, and the chains are further connected into an extensive two-dimensional (2D) framework depending on hydrogen bond.

KW - Chain

KW - Framework

KW - Lanthanide

KW - Polyoxometalate

KW - Sandwich

UR - https://www.scopus.com/pages/publications/33750933497

U2 - 10.1016/j.inoche.2006.08.006

DO - 10.1016/j.inoche.2006.08.006

M3 - 文章

AN - SCOPUS:33750933497

SN - 1387-7003

VL - 9

SP - 1308

EP - 1311

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanion [Ce(PW₁₁O₃₉)₂]^10- and sodium ion linker

Abstract

Keywords

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