A novel coordination polymer [Co(NCS)2(bpms)2]n (bpms = 1,2-bis(4-pyridylmethyl)disulfenyl): Synthesis, crystal structure and third-order nonlinear optical properties

Hongwei Hou; Yinglin Song; Yaoting Fan; Linping Zhang; Chenxia Du; Yu Zhu

doi:10.1016/S0020-1693(01)00391-7

A novel coordination polymer [Co(NCS)₂(bpms)₂]_n (bpms = 1,2-bis(4-pyridylmethyl)disulfenyl): Synthesis, crystal structure and third-order nonlinear optical properties

Hongwei Hou^*
, Yinglin Song
, Yaoting Fan
, Linping Zhang
, Chenxia Du
, Yu Zhu

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

A new 4,4′-bipyridyl-based 'building block', 1,2-bis(4-pyridylmethyl)disulfenyl (bpms) was synthesized. Treatment of the 'building block' with Co(NO₃)₂ and KSCN afforded a new type of one-dimensional (1-D) double zigzag chain coordination polymer [Co(NCS)₂(bpms)₂]_n. Each Co ion is symmetrically bridged by four bpms ligands and also coordinates with two NCS^- anions. The [Co(NCS)₂(bpms)₂]_n can be regarded as a layered structure in the solid state. The 1-D parallel chains are stacked ABAB with a rotation of 90° between A and B. [Co(NCS)₂(bpms)₂]_n in DMF solution also shows very strong third-order nonlinear optical (NLO) properties, its third-order susceptibility χ⁽³⁾ is 1.07 × 10^-11 esu in a 2.8 × 10^-3g cm^-3 DMF solution. The data are comparable to those of C60, phthalocyanine derivations and inorganic clusters. To our knowledge, this is the first reported coordination polymer showing strong third-order NLO properties.

Original language	English
Pages (from-to)	140-144
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	316
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00391-7
State	Published - 7 May 2001

Keywords

Cobalt complexes
Coordination polymer complexes
Crystal structure

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10.1016/S0020-1693(01)00391-7

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@article{78ac4ad2a2cc4c749162734707c5bbd6,

title = "A novel coordination polymer [Co(NCS)2(bpms)2]n (bpms = 1,2-bis(4-pyridylmethyl)disulfenyl): Synthesis, crystal structure and third-order nonlinear optical properties",

abstract = "A new 4,4′-bipyridyl-based 'building block', 1,2-bis(4-pyridylmethyl)disulfenyl (bpms) was synthesized. Treatment of the 'building block' with Co(NO3)2 and KSCN afforded a new type of one-dimensional (1-D) double zigzag chain coordination polymer [Co(NCS)2(bpms)2]n. Each Co ion is symmetrically bridged by four bpms ligands and also coordinates with two NCS- anions. The [Co(NCS)2(bpms)2]n can be regarded as a layered structure in the solid state. The 1-D parallel chains are stacked ABAB with a rotation of 90° between A and B. [Co(NCS)2(bpms)2]n in DMF solution also shows very strong third-order nonlinear optical (NLO) properties, its third-order susceptibility χ(3) is 1.07 {\texttimes} 10-11 esu in a 2.8 {\texttimes} 10-3g cm-3 DMF solution. The data are comparable to those of C60, phthalocyanine derivations and inorganic clusters. To our knowledge, this is the first reported coordination polymer showing strong third-order NLO properties.",

keywords = "Cobalt complexes, Coordination polymer complexes, Crystal structure",

author = "Hongwei Hou and Yinglin Song and Yaoting Fan and Linping Zhang and Chenxia Du and Yu Zhu",

year = "2001",

month = may,

day = "7",

doi = "10.1016/S0020-1693(01)00391-7",

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pages = "140--144",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - A novel coordination polymer [Co(NCS)2(bpms)2]n (bpms = 1,2-bis(4-pyridylmethyl)disulfenyl)

T2 - Synthesis, crystal structure and third-order nonlinear optical properties

AU - Hou, Hongwei

AU - Song, Yinglin

AU - Fan, Yaoting

AU - Zhang, Linping

AU - Du, Chenxia

AU - Zhu, Yu

PY - 2001/5/7

Y1 - 2001/5/7

N2 - A new 4,4′-bipyridyl-based 'building block', 1,2-bis(4-pyridylmethyl)disulfenyl (bpms) was synthesized. Treatment of the 'building block' with Co(NO3)2 and KSCN afforded a new type of one-dimensional (1-D) double zigzag chain coordination polymer [Co(NCS)2(bpms)2]n. Each Co ion is symmetrically bridged by four bpms ligands and also coordinates with two NCS- anions. The [Co(NCS)2(bpms)2]n can be regarded as a layered structure in the solid state. The 1-D parallel chains are stacked ABAB with a rotation of 90° between A and B. [Co(NCS)2(bpms)2]n in DMF solution also shows very strong third-order nonlinear optical (NLO) properties, its third-order susceptibility χ(3) is 1.07 × 10-11 esu in a 2.8 × 10-3g cm-3 DMF solution. The data are comparable to those of C60, phthalocyanine derivations and inorganic clusters. To our knowledge, this is the first reported coordination polymer showing strong third-order NLO properties.

AB - A new 4,4′-bipyridyl-based 'building block', 1,2-bis(4-pyridylmethyl)disulfenyl (bpms) was synthesized. Treatment of the 'building block' with Co(NO3)2 and KSCN afforded a new type of one-dimensional (1-D) double zigzag chain coordination polymer [Co(NCS)2(bpms)2]n. Each Co ion is symmetrically bridged by four bpms ligands and also coordinates with two NCS- anions. The [Co(NCS)2(bpms)2]n can be regarded as a layered structure in the solid state. The 1-D parallel chains are stacked ABAB with a rotation of 90° between A and B. [Co(NCS)2(bpms)2]n in DMF solution also shows very strong third-order nonlinear optical (NLO) properties, its third-order susceptibility χ(3) is 1.07 × 10-11 esu in a 2.8 × 10-3g cm-3 DMF solution. The data are comparable to those of C60, phthalocyanine derivations and inorganic clusters. To our knowledge, this is the first reported coordination polymer showing strong third-order NLO properties.

KW - Cobalt complexes

KW - Coordination polymer complexes

KW - Crystal structure

UR - https://www.scopus.com/pages/publications/0035821401

U2 - 10.1016/S0020-1693(01)00391-7

DO - 10.1016/S0020-1693(01)00391-7

M3 - 文章

AN - SCOPUS:0035821401

SN - 0020-1693

VL - 316

SP - 140

EP - 144

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

A novel coordination polymer [Co(NCS)₂(bpms)₂]_n (bpms = 1,2-bis(4-pyridylmethyl)disulfenyl): Synthesis, crystal structure and third-order nonlinear optical properties

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