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A novel, bipolar polymeric host for highly efficient blue electrophosphorescence: A non-conjugated poly(aryl ether) containing triphenylphosphine oxide units in the electron-transporting main chain and carbazole units in hole-transporting side chains

  • Shiyang Shao
  • , Junqiao Ding*
  • , Tengling Ye
  • , Zhiyuan Xie
  • , Lixiang Wang
  • , Xiabin Jing
  • , Fosong Wang
  • *Corresponding author for this work
  • CAS - Changchun Institute of Applied Chemistry
  • University of Chinese Academy of Sciences

Research output: Contribution to journalArticlepeer-review

Abstract

A novel, bipolar polymeric host based on a poly(aryl ether) containing phosphine oxide units in the electron-transporting main chain and carbazole units in the hole-transporting side chains is designed and synthesized for blue electrophosphorescence. This polymeric host possesses a bipolar character and a high E T of 2.96 eV. The efficiency of blue-emitting PhPLEDs based on this polymeric host doped with FIrpic reaches 23.3 cd A -1 (EQE = 10.8%).

Original languageEnglish
Pages (from-to)3570-3574
Number of pages5
JournalAdvanced Materials
Volume23
Issue number31
DOIs
StatePublished - 16 Aug 2011
Externally publishedYes

Keywords

  • bipolar materials
  • blue phosphorescence
  • high triplet energy
  • poly(aryl ether)s
  • polymeric hosts

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