A novel 3D cadmium coordination polymer constructed from hydrazine and benzene-1,2,4,5-tetracarboxylic acid: Synthesis, structure and fluorescent property

Xiao Yang Yu; Xiao Bing Cui; Xiao Zhang; Li Jin; Ya Nan Luo; Jia Jun Yang; Hong Zhang; Xiang Zhao

doi:10.1016/j.inoche.2011.03.005

A novel 3D cadmium coordination polymer constructed from hydrazine and benzene-1,2,4,5-tetracarboxylic acid: Synthesis, structure and fluorescent property

Xiao Yang Yu
, Xiao Bing Cui
, Xiao Zhang
, Li Jin
, Ya Nan Luo
, Jia Jun Yang
, Hong Zhang^*
, Xiang Zhao

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Northeast Normal University
Jilin Institute of Chemical Technology
College of Chemistry

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

A novel three-dimensional (3D) coordination polymer [Cd(bta) _0.5(N₂H₄)(H₂O)]·H ₂O (1) (H₄bta = benzene-1,2,4,5-tetracarboxylic acid; N₂H₄ = hydrazine) was synthesized hydrothermally and characterized by IR, elemental analysis, TGA and X-ray diffraction analysis. Compound 1 is the first example of 3D coordination compound containing trans-μ₂-bridging ligand N₂H₄. In 1, Cadmium atoms are coordinated by bta^4- ligands to form sinusoidal ruffling layers and the layer are further linked by hydrazine ligands into 3D network with a (8³)(8⁵·10) topology structure. In addition, the thermogravimetric analysis and fluorescent property of compound 1 have been investigated.

Original language	English
Pages (from-to)	848-851
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	6
DOIs	https://doi.org/10.1016/j.inoche.2011.03.005
State	Published - Jun 2011

Keywords

Benzene-1,2,4,5-tetracarboxylate
Coordination polymer
Crystal structure
Hydrazine
Photoluminescence property

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10.1016/j.inoche.2011.03.005

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@article{ad320becd5ef4935afa8f4ec6a5226e9,

title = "A novel 3D cadmium coordination polymer constructed from hydrazine and benzene-1,2,4,5-tetracarboxylic acid: Synthesis, structure and fluorescent property",

abstract = "A novel three-dimensional (3D) coordination polymer [Cd(bta) 0.5(N2H4)(H2O)]·H 2O (1) (H4bta = benzene-1,2,4,5-tetracarboxylic acid; N2H4 = hydrazine) was synthesized hydrothermally and characterized by IR, elemental analysis, TGA and X-ray diffraction analysis. Compound 1 is the first example of 3D coordination compound containing trans-μ2-bridging ligand N2H4. In 1, Cadmium atoms are coordinated by bta4- ligands to form sinusoidal ruffling layers and the layer are further linked by hydrazine ligands into 3D network with a (83)(85·10) topology structure. In addition, the thermogravimetric analysis and fluorescent property of compound 1 have been investigated.",

keywords = "Benzene-1,2,4,5-tetracarboxylate, Coordination polymer, Crystal structure, Hydrazine, Photoluminescence property",

author = "Yu, \{Xiao Yang\} and Cui, \{Xiao Bing\} and Xiao Zhang and Li Jin and Luo, \{Ya Nan\} and Yang, \{Jia Jun\} and Hong Zhang and Xiang Zhao",

year = "2011",

month = jun,

doi = "10.1016/j.inoche.2011.03.005",

language = "英语",

volume = "14",

pages = "848--851",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "6",

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TY - JOUR

T1 - A novel 3D cadmium coordination polymer constructed from hydrazine and benzene-1,2,4,5-tetracarboxylic acid

T2 - Synthesis, structure and fluorescent property

AU - Yu, Xiao Yang

AU - Cui, Xiao Bing

AU - Zhang, Xiao

AU - Jin, Li

AU - Luo, Ya Nan

AU - Yang, Jia Jun

AU - Zhang, Hong

AU - Zhao, Xiang

PY - 2011/6

Y1 - 2011/6

N2 - A novel three-dimensional (3D) coordination polymer [Cd(bta) 0.5(N2H4)(H2O)]·H 2O (1) (H4bta = benzene-1,2,4,5-tetracarboxylic acid; N2H4 = hydrazine) was synthesized hydrothermally and characterized by IR, elemental analysis, TGA and X-ray diffraction analysis. Compound 1 is the first example of 3D coordination compound containing trans-μ2-bridging ligand N2H4. In 1, Cadmium atoms are coordinated by bta4- ligands to form sinusoidal ruffling layers and the layer are further linked by hydrazine ligands into 3D network with a (83)(85·10) topology structure. In addition, the thermogravimetric analysis and fluorescent property of compound 1 have been investigated.

AB - A novel three-dimensional (3D) coordination polymer [Cd(bta) 0.5(N2H4)(H2O)]·H 2O (1) (H4bta = benzene-1,2,4,5-tetracarboxylic acid; N2H4 = hydrazine) was synthesized hydrothermally and characterized by IR, elemental analysis, TGA and X-ray diffraction analysis. Compound 1 is the first example of 3D coordination compound containing trans-μ2-bridging ligand N2H4. In 1, Cadmium atoms are coordinated by bta4- ligands to form sinusoidal ruffling layers and the layer are further linked by hydrazine ligands into 3D network with a (83)(85·10) topology structure. In addition, the thermogravimetric analysis and fluorescent property of compound 1 have been investigated.

KW - Benzene-1,2,4,5-tetracarboxylate

KW - Coordination polymer

KW - Crystal structure

KW - Hydrazine

KW - Photoluminescence property

UR - https://www.scopus.com/pages/publications/79955794262

U2 - 10.1016/j.inoche.2011.03.005

DO - 10.1016/j.inoche.2011.03.005

M3 - 文章

AN - SCOPUS:79955794262

SN - 1387-7003

VL - 14

SP - 848

EP - 851

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

A novel 3D cadmium coordination polymer constructed from hydrazine and benzene-1,2,4,5-tetracarboxylic acid: Synthesis, structure and fluorescent property

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Keywords

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