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A novel 2D layer structure constructed from sandwich-type transition metal substituted tungstates and nickel coordination fragments: {[Ni(enMe)2]2[Ni(enMe)2(H2O)]2[As2W18Ni4(enMe)2O68]}·2H3O·2H2O

  • Zhi Hui Yi
  • , Xiao Bing Cui
  • , Xiao Zhang
  • , Ji Qing Xu*
  • , Guang Di Yang
  • , Yan Chen
  • , Tie Gang Wang
  • , Xiao Yang Yu
  • *Corresponding author for this work
  • College of Chemistry

Research output: Contribution to journalArticlepeer-review

Abstract

A novel polyoxometalate {[Ni(enMe)2]2[Ni(enMe)2(H2O)]2[As2W18Ni4(enMe)2O68]}·2H3O·2H2O (1) (enMe = 1,2-propylenediamine) has been synthesized and characterized, which is the first high-dimensional structure constructed from sandwich-type transition metal substituted tungstates and transition metal coordination groups.

Original languageEnglish
Pages (from-to)149-153
Number of pages5
JournalJournal of Molecular Structure
Volume885
Issue number1-3
DOIs
StatePublished - 14 Aug 2008
Externally publishedYes

Keywords

  • Crystal structure
  • Hydrothermal synthesis
  • Polyoxometalate
  • Sandwich-type cluster

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