A new one-pot synthesis of 2-quaternary 1,3-diketones

S. K. Ren; F. Wang; H. N. Dou; C. A. Fan; L. He; Z. L. Song; W. J. Xia; D. R. Li; Y. X. Jia; X. Li; Y. Q. Tu

doi:10.1055/s-2001-18707

A new one-pot synthesis of 2-quaternary 1,3-diketones

S. K. Ren
, F. Wang
, H. N. Dou
, C. A. Fan
, L. He
, Z. L. Song
, W. J. Xia
, D. R. Li
, Y. X. Jia
, X. Li
, Y. Q. Tu^*

^*Corresponding author for this work

Lanzhou University
Beijing Normal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A facile one-pot synthesis of 1,3-diketones with stereogenic quaternary center at C-2 has been developed on the basis of an oxidative-rearrangement of a series of tertiary α-hydroxy epoxides on treatment with pyridinium chlorochromate (PCC). A possible mechanism is also discussed.

Original language	English
Pages (from-to)	2384-2388
Number of pages	5
Journal	Synthesis (Germany)
Issue number	16
DOIs	https://doi.org/10.1055/s-2001-18707
State	Published - 2001
Externally published	Yes

Keywords

1,3-diketones
Oxidative rearrangement
Pyridinium chlorochromate
Quaternary carbon
Tertiary α-hydroxy epoxides

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10.1055/s-2001-18707

Cite this

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title = "A new one-pot synthesis of 2-quaternary 1,3-diketones",

abstract = "A facile one-pot synthesis of 1,3-diketones with stereogenic quaternary center at C-2 has been developed on the basis of an oxidative-rearrangement of a series of tertiary α-hydroxy epoxides on treatment with pyridinium chlorochromate (PCC). A possible mechanism is also discussed.",

keywords = "1,3-diketones, Oxidative rearrangement, Pyridinium chlorochromate, Quaternary carbon, Tertiary α-hydroxy epoxides",

author = "Ren, \{S. K.\} and F. Wang and Dou, \{H. N.\} and Fan, \{C. A.\} and L. He and Song, \{Z. L.\} and Xia, \{W. J.\} and Li, \{D. R.\} and Jia, \{Y. X.\} and X. Li and Tu, \{Y. Q.\}",

year = "2001",

doi = "10.1055/s-2001-18707",

language = "英语",

pages = "2384--2388",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "16",

}

TY - JOUR

T1 - A new one-pot synthesis of 2-quaternary 1,3-diketones

AU - Ren, S. K.

AU - Wang, F.

AU - Dou, H. N.

AU - Fan, C. A.

AU - He, L.

AU - Song, Z. L.

AU - Xia, W. J.

AU - Li, D. R.

AU - Jia, Y. X.

AU - Li, X.

AU - Tu, Y. Q.

PY - 2001

Y1 - 2001

N2 - A facile one-pot synthesis of 1,3-diketones with stereogenic quaternary center at C-2 has been developed on the basis of an oxidative-rearrangement of a series of tertiary α-hydroxy epoxides on treatment with pyridinium chlorochromate (PCC). A possible mechanism is also discussed.

AB - A facile one-pot synthesis of 1,3-diketones with stereogenic quaternary center at C-2 has been developed on the basis of an oxidative-rearrangement of a series of tertiary α-hydroxy epoxides on treatment with pyridinium chlorochromate (PCC). A possible mechanism is also discussed.

KW - 1,3-diketones

KW - Oxidative rearrangement

KW - Pyridinium chlorochromate

KW - Quaternary carbon

KW - Tertiary α-hydroxy epoxides

UR - https://www.scopus.com/pages/publications/0035206933

U2 - 10.1055/s-2001-18707

DO - 10.1055/s-2001-18707

M3 - 文章

AN - SCOPUS:0035206933

SN - 0039-7881

SP - 2384

EP - 2388

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 16

ER -

A new one-pot synthesis of 2-quaternary 1,3-diketones

Abstract

Keywords

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