A new mixed molybdenum-vanadium polyoxometalate double-supporting transition metal complex: {[Co(phen)2]2-C 2O4} {H2PMo3VIMo 5VV8IVO44[Co(phen) 2(H2O)]2}·7H2O

Ying Hua Sun; Xiao Bing Cui; Guang Hua Li; Ji Qing Xu; Tie Gang Wang; Wei Xu; Ling Yun Pan; Qing Xin Yang

doi:10.1080/00958970500244039

A new mixed molybdenum-vanadium polyoxometalate double-supporting transition metal complex: {[Co(phen)₂]₂-C ₂O₄} {H₂PMo₃^VIMo ₅^VV₈^IVO₄₄[Co(phen) ₂(H₂O)]₂}·7H₂O

Ying Hua Sun
, Xiao Bing Cui
, Guang Hua Li
, Ji Qing Xu^*
, Tie Gang Wang
, Wei Xu
, Ling Yun Pan
, Qing Xin Yang

^*Corresponding author for this work

College of Chemistry
Baicheng Normal University
College of Physics

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The new polyoxometalate double-supporting transition metal complexes, {[Co(phen)₂]₂C₂O₄} {H ₂PMo₃^VIMo₅^VV _8IVO₄₄[Co(phen)₂H₂O] ₂}·7H₂O (1) (phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by single crystal X-ray analysis, IR, XPS, ESR and elemental analysis. Compound 1 is composed of a highly reduced tetra-capped pseudo-Keggin polyoxoanion supporting two transition metal complexes, a binuclear cobalt complex cation and lattice water. The magnetism and third-order non-linear optical properties of 1 have also been studied.

Original language	English
Pages (from-to)	1561-1571
Number of pages	11
Journal	Journal of Coordination Chemistry
Volume	58
Issue number	17
DOIs	https://doi.org/10.1080/00958970500244039
State	Published - 1 Nov 2005
Externally published	Yes

Keywords

Hydrothermal synthesis
Magnetic property
Polyoxometalate
Transition metal

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10.1080/00958970500244039

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@article{b2109719451549b59a8d071ee58b8a14,

title = "A new mixed molybdenum-vanadium polyoxometalate double-supporting transition metal complex: \{[Co(phen)2]2-C 2O4\} \{H2PMo3VIMo 5VV8IVO44[Co(phen) 2(H2O)]2\}·7H2O",

abstract = "The new polyoxometalate double-supporting transition metal complexes, \{[Co(phen)2]2C2O4\} \{H 2PMo3VIMo5VV 8IVO44[Co(phen)2H2O] 2\}·7H2O (1) (phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by single crystal X-ray analysis, IR, XPS, ESR and elemental analysis. Compound 1 is composed of a highly reduced tetra-capped pseudo-Keggin polyoxoanion supporting two transition metal complexes, a binuclear cobalt complex cation and lattice water. The magnetism and third-order non-linear optical properties of 1 have also been studied.",

keywords = "Hydrothermal synthesis, Magnetic property, Polyoxometalate, Transition metal",

author = "Sun, \{Ying Hua\} and Cui, \{Xiao Bing\} and Li, \{Guang Hua\} and Xu, \{Ji Qing\} and Wang, \{Tie Gang\} and Wei Xu and Pan, \{Ling Yun\} and Yang, \{Qing Xin\}",

year = "2005",

month = nov,

day = "1",

doi = "10.1080/00958970500244039",

language = "英语",

volume = "58",

pages = "1561--1571",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "17",

}

TY - JOUR

T1 - A new mixed molybdenum-vanadium polyoxometalate double-supporting transition metal complex

T2 - {[Co(phen)2]2-C 2O4} {H2PMo3VIMo 5VV8IVO44[Co(phen) 2(H2O)]2}·7H2O

AU - Sun, Ying Hua

AU - Cui, Xiao Bing

AU - Li, Guang Hua

AU - Xu, Ji Qing

AU - Wang, Tie Gang

AU - Xu, Wei

AU - Pan, Ling Yun

AU - Yang, Qing Xin

PY - 2005/11/1

Y1 - 2005/11/1

N2 - The new polyoxometalate double-supporting transition metal complexes, {[Co(phen)2]2C2O4} {H 2PMo3VIMo5VV 8IVO44[Co(phen)2H2O] 2}·7H2O (1) (phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by single crystal X-ray analysis, IR, XPS, ESR and elemental analysis. Compound 1 is composed of a highly reduced tetra-capped pseudo-Keggin polyoxoanion supporting two transition metal complexes, a binuclear cobalt complex cation and lattice water. The magnetism and third-order non-linear optical properties of 1 have also been studied.

AB - The new polyoxometalate double-supporting transition metal complexes, {[Co(phen)2]2C2O4} {H 2PMo3VIMo5VV 8IVO44[Co(phen)2H2O] 2}·7H2O (1) (phen = 1,10-phenanthroline) have been hydrothermally synthesized and characterized by single crystal X-ray analysis, IR, XPS, ESR and elemental analysis. Compound 1 is composed of a highly reduced tetra-capped pseudo-Keggin polyoxoanion supporting two transition metal complexes, a binuclear cobalt complex cation and lattice water. The magnetism and third-order non-linear optical properties of 1 have also been studied.

KW - Hydrothermal synthesis

KW - Magnetic property

KW - Polyoxometalate

KW - Transition metal

UR - https://www.scopus.com/pages/publications/30944469596

U2 - 10.1080/00958970500244039

DO - 10.1080/00958970500244039

M3 - 文章

AN - SCOPUS:30944469596

SN - 0095-8972

VL - 58

SP - 1561

EP - 1571

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 17

ER -

A new mixed molybdenum-vanadium polyoxometalate double-supporting transition metal complex: {[Co(phen)₂]₂-C ₂O₄} {H₂PMo₃^VIMo ₅^VV₈^IVO₄₄[Co(phen) ₂(H₂O)]₂}·7H₂O

Abstract

Keywords

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