A new gallium-2,4′-biphenyldicarboxylate layer structure with parallelogram tunnels

Guangpeng Zhou; Yulin Yang; Ruiqing Fan

doi:10.1016/j.inoche.2011.11.018

A new gallium-2,4′-biphenyldicarboxylate layer structure with parallelogram tunnels

Guangpeng Zhou
, Yulin Yang^*
, Ruiqing Fan

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A new 2D gallium metal-organic framework formulated as Ga(OH)(BPDA) (1) (H ₂BPDA = 2,4′-biphenyldicarboxylic acid, C ₁₄O ₄H ₁₀) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA) and luminescence studies. The neutral layer structure of the coordination polymer 1 is constructed from GaO ₄(OH) ₂ octahedra and organic BPDA ^2- linkers, with the parallelogram tunnels joined through one-dimensional OHGaOH chains. Complex 1 exhibits intense green-blue emission at 482 nm (λ _ex = 329 nm) in the solid state at room temperature.

Original language	English
Pages (from-to)	17-20
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	16
DOIs	https://doi.org/10.1016/j.inoche.2011.11.018
State	Published - Feb 2012

Keywords

Crystal structure
Gallium
Hydrothermal synthesis
Metal-organic framework

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10.1016/j.inoche.2011.11.018

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title = "A new gallium-2,4′-biphenyldicarboxylate layer structure with parallelogram tunnels",

abstract = "A new 2D gallium metal-organic framework formulated as Ga(OH)(BPDA) (1) (H 2BPDA = 2,4′-biphenyldicarboxylic acid, C 14O 4H 10) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA) and luminescence studies. The neutral layer structure of the coordination polymer 1 is constructed from GaO 4(OH) 2 octahedra and organic BPDA 2- linkers, with the parallelogram tunnels joined through one-dimensional OHGaOH chains. Complex 1 exhibits intense green-blue emission at 482 nm (λ ex = 329 nm) in the solid state at room temperature.",

keywords = "Crystal structure, Gallium, Hydrothermal synthesis, Metal-organic framework",

author = "Guangpeng Zhou and Yulin Yang and Ruiqing Fan",

year = "2012",

month = feb,

doi = "10.1016/j.inoche.2011.11.018",

language = "英语",

volume = "16",

pages = "17--20",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A new gallium-2,4′-biphenyldicarboxylate layer structure with parallelogram tunnels

AU - Zhou, Guangpeng

AU - Yang, Yulin

AU - Fan, Ruiqing

PY - 2012/2

Y1 - 2012/2

N2 - A new 2D gallium metal-organic framework formulated as Ga(OH)(BPDA) (1) (H 2BPDA = 2,4′-biphenyldicarboxylic acid, C 14O 4H 10) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA) and luminescence studies. The neutral layer structure of the coordination polymer 1 is constructed from GaO 4(OH) 2 octahedra and organic BPDA 2- linkers, with the parallelogram tunnels joined through one-dimensional OHGaOH chains. Complex 1 exhibits intense green-blue emission at 482 nm (λ ex = 329 nm) in the solid state at room temperature.

AB - A new 2D gallium metal-organic framework formulated as Ga(OH)(BPDA) (1) (H 2BPDA = 2,4′-biphenyldicarboxylic acid, C 14O 4H 10) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, infrared (IR) spectroscopy, thermal gravimetric analysis (TGA) and luminescence studies. The neutral layer structure of the coordination polymer 1 is constructed from GaO 4(OH) 2 octahedra and organic BPDA 2- linkers, with the parallelogram tunnels joined through one-dimensional OHGaOH chains. Complex 1 exhibits intense green-blue emission at 482 nm (λ ex = 329 nm) in the solid state at room temperature.

KW - Crystal structure

KW - Gallium

KW - Hydrothermal synthesis

KW - Metal-organic framework

UR - https://www.scopus.com/pages/publications/84855649973

U2 - 10.1016/j.inoche.2011.11.018

DO - 10.1016/j.inoche.2011.11.018

M3 - 文章

AN - SCOPUS:84855649973

SN - 1387-7003

VL - 16

SP - 17

EP - 20

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A new gallium-2,4′-biphenyldicarboxylate layer structure with parallelogram tunnels

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Keywords

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