A new coordination polymer containing 4-[(8-hydroxy-5-quinolinyl)azo]- benzenesulfonic acid: Synthesis, structure and fluorescent property

Ya Nan Luo; Xian Zhu Xu; Xiao Yang Yu; Guang Shan Zhu; Xiao Zhang; Xiao Shu Qu; Li Ying Yu

A new coordination polymer containing 4-[(8-hydroxy-5-quinolinyl)azo]- benzenesulfonic acid: Synthesis, structure and fluorescent property

Ya Nan Luo
, Xian Zhu Xu^*
, Xiao Yang Yu
, Guang Shan Zhu
, Xiao Zhang
, Xiao Shu Qu
, Li Ying Yu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A new coordination polymer, {[CdL(en)]·DMF}_n (1, H ₂L = 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, en = ethylenediamine, DMF = N,N-dimethylformamide), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared (IR) spectra, elemental analysis, powder X-ray diffractions (PXRD) and thermogravimetric analysis (TGA). Compound 1 crystallizes in monoclinic, space group P21/c with a = 14.6525(9), b = 13.3917(9), c = 11.8838(8) Å, β = 101.2290(10)°, V = 2287.2(3) Å³, Z = 4, C ₂₀H₂₄CdN₆O₅S, M_r = 572.91, D_c = 1.664 mg·mm^-3, F(000) = 1160, μ = 1.091 mm^-1, R = 0.0232 and wR = 0.0587 for 3597 observed reflections (I > 2σ(I)). Compound 1 exhibits a one-dimensional (1D) double-chain structure which is further connected through hydrogen bonding and π-π interactions into a three-dimensional (3D) supramolecular network. In addition, it exhibits blue fluorescence at room temperature in the solid state.

Original language	English
Pages (from-to)	1667-1672
Number of pages	6
Journal	Jiegou Huaxue
Volume	32
Issue number	11
State	Published - 15 Nov 2013

Keywords

4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid
Coordination polymer
Fluorescent property

Cite this

@article{1e022d9fd5b244c8931fb7be06cd303a,

title = "A new coordination polymer containing 4-[(8-hydroxy-5-quinolinyl)azo]- benzenesulfonic acid: Synthesis, structure and fluorescent property",

abstract = "A new coordination polymer, \{[CdL(en)]·DMF\}n (1, H 2L = 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, en = ethylenediamine, DMF = N,N-dimethylformamide), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared (IR) spectra, elemental analysis, powder X-ray diffractions (PXRD) and thermogravimetric analysis (TGA). Compound 1 crystallizes in monoclinic, space group P21/c with a = 14.6525(9), b = 13.3917(9), c = 11.8838(8) {\AA}, β = 101.2290(10)°, V = 2287.2(3) {\AA}3, Z = 4, C 20H24CdN6O5S, Mr = 572.91, Dc = 1.664 mg·mm-3, F(000) = 1160, μ = 1.091 mm-1, R = 0.0232 and wR = 0.0587 for 3597 observed reflections (I > 2σ(I)). Compound 1 exhibits a one-dimensional (1D) double-chain structure which is further connected through hydrogen bonding and π-π interactions into a three-dimensional (3D) supramolecular network. In addition, it exhibits blue fluorescence at room temperature in the solid state.",

keywords = "4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, Coordination polymer, Fluorescent property",

author = "Luo, \{Ya Nan\} and Xu, \{Xian Zhu\} and Yu, \{Xiao Yang\} and Zhu, \{Guang Shan\} and Xiao Zhang and Qu, \{Xiao Shu\} and Yu, \{Li Ying\}",

year = "2013",

month = nov,

day = "15",

language = "英语",

volume = "32",

pages = "1667--1672",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "11",

}

TY - JOUR

T1 - A new coordination polymer containing 4-[(8-hydroxy-5-quinolinyl)azo]- benzenesulfonic acid

T2 - Synthesis, structure and fluorescent property

AU - Luo, Ya Nan

AU - Xu, Xian Zhu

AU - Yu, Xiao Yang

AU - Zhu, Guang Shan

AU - Zhang, Xiao

AU - Qu, Xiao Shu

AU - Yu, Li Ying

PY - 2013/11/15

Y1 - 2013/11/15

N2 - A new coordination polymer, {[CdL(en)]·DMF}n (1, H 2L = 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, en = ethylenediamine, DMF = N,N-dimethylformamide), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared (IR) spectra, elemental analysis, powder X-ray diffractions (PXRD) and thermogravimetric analysis (TGA). Compound 1 crystallizes in monoclinic, space group P21/c with a = 14.6525(9), b = 13.3917(9), c = 11.8838(8) Å, β = 101.2290(10)°, V = 2287.2(3) Å3, Z = 4, C 20H24CdN6O5S, Mr = 572.91, Dc = 1.664 mg·mm-3, F(000) = 1160, μ = 1.091 mm-1, R = 0.0232 and wR = 0.0587 for 3597 observed reflections (I > 2σ(I)). Compound 1 exhibits a one-dimensional (1D) double-chain structure which is further connected through hydrogen bonding and π-π interactions into a three-dimensional (3D) supramolecular network. In addition, it exhibits blue fluorescence at room temperature in the solid state.

AB - A new coordination polymer, {[CdL(en)]·DMF}n (1, H 2L = 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid, en = ethylenediamine, DMF = N,N-dimethylformamide), has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction, infrared (IR) spectra, elemental analysis, powder X-ray diffractions (PXRD) and thermogravimetric analysis (TGA). Compound 1 crystallizes in monoclinic, space group P21/c with a = 14.6525(9), b = 13.3917(9), c = 11.8838(8) Å, β = 101.2290(10)°, V = 2287.2(3) Å3, Z = 4, C 20H24CdN6O5S, Mr = 572.91, Dc = 1.664 mg·mm-3, F(000) = 1160, μ = 1.091 mm-1, R = 0.0232 and wR = 0.0587 for 3597 observed reflections (I > 2σ(I)). Compound 1 exhibits a one-dimensional (1D) double-chain structure which is further connected through hydrogen bonding and π-π interactions into a three-dimensional (3D) supramolecular network. In addition, it exhibits blue fluorescence at room temperature in the solid state.

KW - 4-[(8-hydroxy-5-quinolinyl)azo]-benzenesulfonic acid

KW - Coordination polymer

KW - Fluorescent property

UR - https://www.scopus.com/pages/publications/84903633116

M3 - 文章

AN - SCOPUS:84903633116

SN - 0254-5861

VL - 32

SP - 1667

EP - 1672

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 11

ER -

A new coordination polymer containing 4-[(8-hydroxy-5-quinolinyl)azo]- benzenesulfonic acid: Synthesis, structure and fluorescent property

Abstract

Keywords

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