A new compound based on polyoxoniobates and three types of copper complexes

Po Han Lin; Hai Yang Guo; Xiao Zhang; Xiao Bing Cui; Qi Sheng Huo; Ji Qing Xu

doi:10.1016/j.inoche.2016.09.014

A new compound based on polyoxoniobates and three types of copper complexes

Po Han Lin
, Hai Yang Guo
, Xiao Zhang^*
, Xiao Bing Cui
, Qi Sheng Huo
, Ji Qing Xu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new compound based on bi-capped Keggin polyoxoniobates and copper coordination complexes, with formula [Cu(en)₂][Cu(en)₂(H₂O)₂][Cu(en)₂(H₂O)]₂[H₄SiNb₁₂V₂O₄₂]·7H₂O (1) (en = ethylenediamine), was obtained under hydrothermal condition and characterized by single crystal X-ray diffraction, infrared spectrum (IR), powder X-ray diffraction (PXRD), Ultraviolet–visible spectroscopy (UV–vis) and electron spin resonance (ESR) analysis. Compound 1 has three different types of copper complexes in it. A [Cu(en)₂]^2 + and two [Cu(en)₂(H₂O)]^2 + fragments were supported by the polyoxoniobate to form a novel polyoxoniobate tri-supported coordination complex.

Original language	English
Pages (from-to)	34-36
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	73
DOIs	https://doi.org/10.1016/j.inoche.2016.09.014
State	Published - 1 Nov 2016
Externally published	Yes

Keywords

Bi-capped Keggin
Hydrothermal
Polyoxoniobates
Single-crystal
Tri-supported complex

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10.1016/j.inoche.2016.09.014

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@article{68cdfb184dc04b6caf043677398ca156,

title = "A new compound based on polyoxoniobates and three types of copper complexes",

abstract = "A new compound based on bi-capped Keggin polyoxoniobates and copper coordination complexes, with formula [Cu(en)2][Cu(en)2(H2O)2][Cu(en)2(H2O)]2[H4SiNb12V2O42]·7H2O (1) (en = ethylenediamine), was obtained under hydrothermal condition and characterized by single crystal X-ray diffraction, infrared spectrum (IR), powder X-ray diffraction (PXRD), Ultraviolet–visible spectroscopy (UV–vis) and electron spin resonance (ESR) analysis. Compound 1 has three different types of copper complexes in it. A [Cu(en)2]2 + and two [Cu(en)2(H2O)]2 + fragments were supported by the polyoxoniobate to form a novel polyoxoniobate tri-supported coordination complex.",

keywords = "Bi-capped Keggin, Hydrothermal, Polyoxoniobates, Single-crystal, Tri-supported complex",

author = "Lin, \{Po Han\} and Guo, \{Hai Yang\} and Xiao Zhang and Cui, \{Xiao Bing\} and Huo, \{Qi Sheng\} and Xu, \{Ji Qing\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = nov,

day = "1",

doi = "10.1016/j.inoche.2016.09.014",

language = "英语",

volume = "73",

pages = "34--36",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A new compound based on polyoxoniobates and three types of copper complexes

AU - Lin, Po Han

AU - Guo, Hai Yang

AU - Zhang, Xiao

AU - Cui, Xiao Bing

AU - Huo, Qi Sheng

AU - Xu, Ji Qing

PY - 2016/11/1

Y1 - 2016/11/1

N2 - A new compound based on bi-capped Keggin polyoxoniobates and copper coordination complexes, with formula [Cu(en)2][Cu(en)2(H2O)2][Cu(en)2(H2O)]2[H4SiNb12V2O42]·7H2O (1) (en = ethylenediamine), was obtained under hydrothermal condition and characterized by single crystal X-ray diffraction, infrared spectrum (IR), powder X-ray diffraction (PXRD), Ultraviolet–visible spectroscopy (UV–vis) and electron spin resonance (ESR) analysis. Compound 1 has three different types of copper complexes in it. A [Cu(en)2]2 + and two [Cu(en)2(H2O)]2 + fragments were supported by the polyoxoniobate to form a novel polyoxoniobate tri-supported coordination complex.

AB - A new compound based on bi-capped Keggin polyoxoniobates and copper coordination complexes, with formula [Cu(en)2][Cu(en)2(H2O)2][Cu(en)2(H2O)]2[H4SiNb12V2O42]·7H2O (1) (en = ethylenediamine), was obtained under hydrothermal condition and characterized by single crystal X-ray diffraction, infrared spectrum (IR), powder X-ray diffraction (PXRD), Ultraviolet–visible spectroscopy (UV–vis) and electron spin resonance (ESR) analysis. Compound 1 has three different types of copper complexes in it. A [Cu(en)2]2 + and two [Cu(en)2(H2O)]2 + fragments were supported by the polyoxoniobate to form a novel polyoxoniobate tri-supported coordination complex.

KW - Bi-capped Keggin

KW - Hydrothermal

KW - Polyoxoniobates

KW - Single-crystal

KW - Tri-supported complex

UR - https://www.scopus.com/pages/publications/84988373658

U2 - 10.1016/j.inoche.2016.09.014

DO - 10.1016/j.inoche.2016.09.014

M3 - 文章

AN - SCOPUS:84988373658

SN - 1387-7003

VL - 73

SP - 34

EP - 36

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A new compound based on polyoxoniobates and three types of copper complexes

Abstract

Keywords

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