A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid

Xiao Yang Yu; Xiao Zhang; Xiao Shu Qu; Ming Shuo Ma; Zhi Gang Liu; Li Jin; Yan Yan Yang; Ya Nan Luo

doi:10.1080/00958972.2015.1075240

A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid

Xiao Yang Yu
, Xiao Zhang^*
, Xiao Shu Qu
, Ming Shuo Ma
, Zhi Gang Liu
, Li Jin
, Yan Yan Yang
, Ya Nan Luo

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Jilin Institute of Chemical Technology

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new metal-organic framework based on a multifunctional ligand, 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid (H₃PIDC), [Cd(HPIDC)]_n (1), has been obtained under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectrum, and powder X-ray diffraction. Compound 1 is constructed by metallacalix[4]arene building blocks Cd₄(HPIDC)₄ with single-left (L) and single-right-helical (R) chains sitting on the four corners of Cd₄(HPIDC)₄ units. The structure of 1 can be described as a (3,3)-connected net with the (8²× 10) topology. The solid-state photoluminescence has been carried out at room temperature.

Original language	English
Pages (from-to)	3580-3588
Number of pages	9
Journal	Journal of Coordination Chemistry
Volume	68
Issue number	20
DOIs	https://doi.org/10.1080/00958972.2015.1075240
State	Published - 18 Oct 2015

Keywords

Cd(II) coordination polymer
Metallacalix[4]arene building block
Photoluminescence property

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10.1080/00958972.2015.1075240

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@article{2b04638ea17b4af08ef6ca6f35f1d73f,

title = "A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid",

abstract = "A new metal-organic framework based on a multifunctional ligand, 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid (H3PIDC), [Cd(HPIDC)]n (1), has been obtained under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectrum, and powder X-ray diffraction. Compound 1 is constructed by metallacalix[4]arene building blocks Cd4(HPIDC)4 with single-left (L) and single-right-helical (R) chains sitting on the four corners of Cd4(HPIDC)4 units. The structure of 1 can be described as a (3,3)-connected net with the (82× 10) topology. The solid-state photoluminescence has been carried out at room temperature.",

keywords = "Cd(II) coordination polymer, Metallacalix[4]arene building block, Photoluminescence property",

author = "Yu, \{Xiao Yang\} and Xiao Zhang and Qu, \{Xiao Shu\} and Ma, \{Ming Shuo\} and Liu, \{Zhi Gang\} and Li Jin and Yang, \{Yan Yan\} and Luo, \{Ya Nan\}",

note = "Publisher Copyright: {\textcopyright} 2015 Taylor \& Francis.",

year = "2015",

month = oct,

day = "18",

doi = "10.1080/00958972.2015.1075240",

language = "英语",

volume = "68",

pages = "3580--3588",

journal = "Journal of Coordination Chemistry",

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T1 - A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid

AU - Yu, Xiao Yang

AU - Zhang, Xiao

AU - Qu, Xiao Shu

AU - Ma, Ming Shuo

AU - Liu, Zhi Gang

AU - Jin, Li

AU - Yang, Yan Yan

AU - Luo, Ya Nan

PY - 2015/10/18

Y1 - 2015/10/18

N2 - A new metal-organic framework based on a multifunctional ligand, 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid (H3PIDC), [Cd(HPIDC)]n (1), has been obtained under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectrum, and powder X-ray diffraction. Compound 1 is constructed by metallacalix[4]arene building blocks Cd4(HPIDC)4 with single-left (L) and single-right-helical (R) chains sitting on the four corners of Cd4(HPIDC)4 units. The structure of 1 can be described as a (3,3)-connected net with the (82× 10) topology. The solid-state photoluminescence has been carried out at room temperature.

AB - A new metal-organic framework based on a multifunctional ligand, 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid (H3PIDC), [Cd(HPIDC)]n (1), has been obtained under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectrum, and powder X-ray diffraction. Compound 1 is constructed by metallacalix[4]arene building blocks Cd4(HPIDC)4 with single-left (L) and single-right-helical (R) chains sitting on the four corners of Cd4(HPIDC)4 units. The structure of 1 can be described as a (3,3)-connected net with the (82× 10) topology. The solid-state photoluminescence has been carried out at room temperature.

KW - Cd(II) coordination polymer

KW - Metallacalix[4]arene building block

KW - Photoluminescence property

UR - https://www.scopus.com/pages/publications/84941744947

U2 - 10.1080/00958972.2015.1075240

DO - 10.1080/00958972.2015.1075240

M3 - 文章

AN - SCOPUS:84941744947

SN - 0095-8972

VL - 68

SP - 3580

EP - 3588

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 20

ER -

A new 3-D Cd(II) coordination polymer with metallacalix[4]arene building blocks based on 2-(pyridin-2-yl)-1H-imidazole-4,5-dicarboxylic acid

Abstract

Keywords

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