A MOF material based on zinc (II) and mixed ligands: Synthesis, structure and luminescence behavior

Xiao Zhang; Chunyu Ge; N. Zhang; Yuanling Duan; Yan Wang; L. Zhao; Xinrui Zhuang; Jinxue Li; Jie Wu; Qingfeng Yang

doi:10.1016/j.ica.2019.119035

A MOF material based on zinc (II) and mixed ligands: Synthesis, structure and luminescence behavior

Xiao Zhang^*
, Chunyu Ge
, N. Zhang
, Yuanling Duan
, Yan Wang
, L. Zhao
, Xinrui Zhuang
, Jinxue Li
, Jie Wu
, Qingfeng Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
School of Life Science and Technology, Harbin Institute of Technology
Heilongjiang University
Ningxia University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

In this work, a novel three-dimensional (3D) complex [Zn₂(bta)(ppda)]_n(1) (H₄bta = 1,2,4,5-benzenetetracarboxylic acid, ppda = p-phenylenediamine) has been synthesized under hydrothermal condition. Complex 1 exhibits high sensitivities towards the nitroaromatics (NACs) and Fe³⁺ ions in dimethylsulfoxide (DMSO) solution via fluorescence quenching. Specially, 1 as a fluorescence probe for sensing the Fe³⁺ ions has a large quenching coefficient K_sv of 8.823 × 10⁶ M⁻¹ and a low limit of detection (LOD) of 4.664 × 10⁻⁴ μM.

Original language	English
Article number	119035
Journal	Inorganica Chimica Acta
Volume	496
DOIs	https://doi.org/10.1016/j.ica.2019.119035
State	Published - 1 Oct 2019
Externally published	Yes

Keywords

Fe ion
Fluorescence probe
Nitroaromatics
Zn-MOF

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10.1016/j.ica.2019.119035

Cite this

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title = "A MOF material based on zinc (II) and mixed ligands: Synthesis, structure and luminescence behavior",

abstract = "In this work, a novel three-dimensional (3D) complex [Zn2(bta)(ppda)]n(1) (H4bta = 1,2,4,5-benzenetetracarboxylic acid, ppda = p-phenylenediamine) has been synthesized under hydrothermal condition. Complex 1 exhibits high sensitivities towards the nitroaromatics (NACs) and Fe3+ ions in dimethylsulfoxide (DMSO) solution via fluorescence quenching. Specially, 1 as a fluorescence probe for sensing the Fe3+ ions has a large quenching coefficient Ksv of 8.823 {\texttimes} 106 M−1 and a low limit of detection (LOD) of 4.664 {\texttimes} 10−4 μM.",

keywords = "Fe ion, Fluorescence probe, Nitroaromatics, Zn-MOF",

author = "Xiao Zhang and Chunyu Ge and N. Zhang and Yuanling Duan and Yan Wang and L. Zhao and Xinrui Zhuang and Jinxue Li and Jie Wu and Qingfeng Yang",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",

year = "2019",

month = oct,

day = "1",

doi = "10.1016/j.ica.2019.119035",

language = "英语",

volume = "496",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - A MOF material based on zinc (II) and mixed ligands

T2 - Synthesis, structure and luminescence behavior

AU - Zhang, Xiao

AU - Ge, Chunyu

AU - Zhang, N.

AU - Duan, Yuanling

AU - Wang, Yan

AU - Zhao, L.

AU - Zhuang, Xinrui

AU - Li, Jinxue

AU - Wu, Jie

AU - Yang, Qingfeng

PY - 2019/10/1

Y1 - 2019/10/1

N2 - In this work, a novel three-dimensional (3D) complex [Zn2(bta)(ppda)]n(1) (H4bta = 1,2,4,5-benzenetetracarboxylic acid, ppda = p-phenylenediamine) has been synthesized under hydrothermal condition. Complex 1 exhibits high sensitivities towards the nitroaromatics (NACs) and Fe3+ ions in dimethylsulfoxide (DMSO) solution via fluorescence quenching. Specially, 1 as a fluorescence probe for sensing the Fe3+ ions has a large quenching coefficient Ksv of 8.823 × 106 M−1 and a low limit of detection (LOD) of 4.664 × 10−4 μM.

AB - In this work, a novel three-dimensional (3D) complex [Zn2(bta)(ppda)]n(1) (H4bta = 1,2,4,5-benzenetetracarboxylic acid, ppda = p-phenylenediamine) has been synthesized under hydrothermal condition. Complex 1 exhibits high sensitivities towards the nitroaromatics (NACs) and Fe3+ ions in dimethylsulfoxide (DMSO) solution via fluorescence quenching. Specially, 1 as a fluorescence probe for sensing the Fe3+ ions has a large quenching coefficient Ksv of 8.823 × 106 M−1 and a low limit of detection (LOD) of 4.664 × 10−4 μM.

KW - Fe ion

KW - Fluorescence probe

KW - Nitroaromatics

KW - Zn-MOF

UR - https://www.scopus.com/pages/publications/85069746486

U2 - 10.1016/j.ica.2019.119035

DO - 10.1016/j.ica.2019.119035

M3 - 文章

AN - SCOPUS:85069746486

SN - 0020-1693

VL - 496

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 119035

ER -

A MOF material based on zinc (II) and mixed ligands: Synthesis, structure and luminescence behavior

Abstract

Keywords

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