A metal-free addition/dearomatization-cyclization/decarboxylation cascade of aryl 3-arylpropiolate toward the synthesis of 1,1-diaryl-2-alkyl-substituted ethylenes

Jie Wang; Xue Qing Mou; Bang Hong Zhang; Wei Ting Liu; Chao Yang; Li Xu; Zheng Liang Xu; Shao Hua Wang

doi:10.1016/j.tetlet.2016.02.013

A metal-free addition/dearomatization-cyclization/decarboxylation cascade of aryl 3-arylpropiolate toward the synthesis of 1,1-diaryl-2-alkyl-substituted ethylenes

Jie Wang
, Xue Qing Mou
, Bang Hong Zhang
, Wei Ting Liu
, Chao Yang
, Li Xu
, Zheng Liang Xu
, Shao Hua Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A radical-participated addition/dearomatization-cyclization/decarboxylation cascade between aryl 3-arylpropiolate and ethers (cycloalkane) has been developed to give a series of 1,1,2-trisubstituted ethylenes in moderate to good yields.

Original language	English
Pages (from-to)	1239-1242
Number of pages	4
Journal	Tetrahedron Letters
Volume	57
Issue number	11
DOIs	https://doi.org/10.1016/j.tetlet.2016.02.013
State	Published - 16 Mar 2016
Externally published	Yes

Keywords

1,1,2-Trisubstituted ethylenes
Aryl 3-arylpropiolate
Decarboxylation
Tandem reaction

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10.1016/j.tetlet.2016.02.013

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title = "A metal-free addition/dearomatization-cyclization/decarboxylation cascade of aryl 3-arylpropiolate toward the synthesis of 1,1-diaryl-2-alkyl-substituted ethylenes",

abstract = "A radical-participated addition/dearomatization-cyclization/decarboxylation cascade between aryl 3-arylpropiolate and ethers (cycloalkane) has been developed to give a series of 1,1,2-trisubstituted ethylenes in moderate to good yields.",

keywords = "1,1,2-Trisubstituted ethylenes, Aryl 3-arylpropiolate, Decarboxylation, Tandem reaction",

author = "Jie Wang and Mou, \{Xue Qing\} and Zhang, \{Bang Hong\} and Liu, \{Wei Ting\} and Chao Yang and Li Xu and Xu, \{Zheng Liang\} and Wang, \{Shao Hua\}",

year = "2016",

month = mar,

day = "16",

doi = "10.1016/j.tetlet.2016.02.013",

language = "英语",

volume = "57",

pages = "1239--1242",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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number = "11",

}

TY - JOUR

T1 - A metal-free addition/dearomatization-cyclization/decarboxylation cascade of aryl 3-arylpropiolate toward the synthesis of 1,1-diaryl-2-alkyl-substituted ethylenes

AU - Wang, Jie

AU - Mou, Xue Qing

AU - Zhang, Bang Hong

AU - Liu, Wei Ting

AU - Yang, Chao

AU - Xu, Li

AU - Xu, Zheng Liang

AU - Wang, Shao Hua

PY - 2016/3/16

Y1 - 2016/3/16

N2 - A radical-participated addition/dearomatization-cyclization/decarboxylation cascade between aryl 3-arylpropiolate and ethers (cycloalkane) has been developed to give a series of 1,1,2-trisubstituted ethylenes in moderate to good yields.

AB - A radical-participated addition/dearomatization-cyclization/decarboxylation cascade between aryl 3-arylpropiolate and ethers (cycloalkane) has been developed to give a series of 1,1,2-trisubstituted ethylenes in moderate to good yields.

KW - 1,1,2-Trisubstituted ethylenes

KW - Aryl 3-arylpropiolate

KW - Decarboxylation

KW - Tandem reaction

UR - https://www.scopus.com/pages/publications/84958883802

U2 - 10.1016/j.tetlet.2016.02.013

DO - 10.1016/j.tetlet.2016.02.013

M3 - 文章

AN - SCOPUS:84958883802

SN - 0040-4039

VL - 57

SP - 1239

EP - 1242

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 11

ER -

A metal-free addition/dearomatization-cyclization/decarboxylation cascade of aryl 3-arylpropiolate toward the synthesis of 1,1-diaryl-2-alkyl-substituted ethylenes

Abstract

Keywords

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