A graphene oxide-based molecularly imprinted polymer platform for detecting endocrine disrupting chemicals

Ying Li; Xin Li; Cunku Dong; Jingyao Qi; Xijiang Han

doi:10.1016/j.carbon.2010.05.038

A graphene oxide-based molecularly imprinted polymer platform for detecting endocrine disrupting chemicals

Ying Li
, Xin Li^*
, Cunku Dong
, Jingyao Qi
, Xijiang Han

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

164 Scopus citations

Abstract

A molecularly imprinted polymer-graphene oxide (MIP-GO) hybrid material was synthesized by reversible addition and fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized GO as chain transfer agent. The formation of this hybrid material was verified by Raman spectroscopy, Fourier transform infrared spectroscopy, and thermal gravimetric analysis. Atomic force microscopy showed that the average thickness of the polymer grafted on the GO surface is about 3.70 nm. The resulting GO-MIP hybrids showed outstanding affinity towards 2,4-dichlorophenol (2,4-DCP) in aqueous solution. The GO-MIP hybrids bind the original template 2,4-DCP with an appreciable selectivity over structurally related compounds. Density functional theory calculations verified the mechanism of the significant improvements on the affinity and selectivity of the MIP-functionalized graphene materials.

Original language	English
Pages (from-to)	3427-3433
Number of pages	7
Journal	Carbon
Volume	48
Issue number	12
DOIs	https://doi.org/10.1016/j.carbon.2010.05.038
State	Published - Oct 2010

Access to Document

10.1016/j.carbon.2010.05.038

Cite this

@article{edae9a719157459fb90b07b92e615b5d,

title = "A graphene oxide-based molecularly imprinted polymer platform for detecting endocrine disrupting chemicals",

abstract = "A molecularly imprinted polymer-graphene oxide (MIP-GO) hybrid material was synthesized by reversible addition and fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized GO as chain transfer agent. The formation of this hybrid material was verified by Raman spectroscopy, Fourier transform infrared spectroscopy, and thermal gravimetric analysis. Atomic force microscopy showed that the average thickness of the polymer grafted on the GO surface is about 3.70 nm. The resulting GO-MIP hybrids showed outstanding affinity towards 2,4-dichlorophenol (2,4-DCP) in aqueous solution. The GO-MIP hybrids bind the original template 2,4-DCP with an appreciable selectivity over structurally related compounds. Density functional theory calculations verified the mechanism of the significant improvements on the affinity and selectivity of the MIP-functionalized graphene materials.",

author = "Ying Li and Xin Li and Cunku Dong and Jingyao Qi and Xijiang Han",

year = "2010",

month = oct,

doi = "10.1016/j.carbon.2010.05.038",

language = "英语",

volume = "48",

pages = "3427--3433",

journal = "Carbon",

issn = "0008-6223",

publisher = "Elsevier Ltd",

number = "12",

}

TY - JOUR

T1 - A graphene oxide-based molecularly imprinted polymer platform for detecting endocrine disrupting chemicals

AU - Li, Ying

AU - Li, Xin

AU - Dong, Cunku

AU - Qi, Jingyao

AU - Han, Xijiang

PY - 2010/10

Y1 - 2010/10

N2 - A molecularly imprinted polymer-graphene oxide (MIP-GO) hybrid material was synthesized by reversible addition and fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized GO as chain transfer agent. The formation of this hybrid material was verified by Raman spectroscopy, Fourier transform infrared spectroscopy, and thermal gravimetric analysis. Atomic force microscopy showed that the average thickness of the polymer grafted on the GO surface is about 3.70 nm. The resulting GO-MIP hybrids showed outstanding affinity towards 2,4-dichlorophenol (2,4-DCP) in aqueous solution. The GO-MIP hybrids bind the original template 2,4-DCP with an appreciable selectivity over structurally related compounds. Density functional theory calculations verified the mechanism of the significant improvements on the affinity and selectivity of the MIP-functionalized graphene materials.

AB - A molecularly imprinted polymer-graphene oxide (MIP-GO) hybrid material was synthesized by reversible addition and fragmentation chain transfer (RAFT) polymerization using RAFT agent functionalized GO as chain transfer agent. The formation of this hybrid material was verified by Raman spectroscopy, Fourier transform infrared spectroscopy, and thermal gravimetric analysis. Atomic force microscopy showed that the average thickness of the polymer grafted on the GO surface is about 3.70 nm. The resulting GO-MIP hybrids showed outstanding affinity towards 2,4-dichlorophenol (2,4-DCP) in aqueous solution. The GO-MIP hybrids bind the original template 2,4-DCP with an appreciable selectivity over structurally related compounds. Density functional theory calculations verified the mechanism of the significant improvements on the affinity and selectivity of the MIP-functionalized graphene materials.

UR - https://www.scopus.com/pages/publications/77955425549

U2 - 10.1016/j.carbon.2010.05.038

DO - 10.1016/j.carbon.2010.05.038

M3 - 文章

AN - SCOPUS:77955425549

SN - 0008-6223

VL - 48

SP - 3427

EP - 3433

JO - Carbon

JF - Carbon

IS - 12

ER -

A graphene oxide-based molecularly imprinted polymer platform for detecting endocrine disrupting chemicals

Abstract

Access to Document

Other files and links

Fingerprint

Cite this