A general approach from eudesmane to isodaucane sesquiterpenes: Synthesis of 7-epi-14-isocyano-isodauc-5-ene from α-(-)-santonin

De Run Li; Wu Jiong Xia; Lei Shi; Yong Qiang Tu

A general approach from eudesmane to isodaucane sesquiterpenes: Synthesis of 7-epi-14-isocyano-isodauc-5-ene from α-(-)-santonin

De Run Li
, Wu Jiong Xia
, Lei Shi
, Yong Qiang Tu^*

^*Corresponding author for this work

Lanzhou University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A general and efficient approach for synthesis of an isodaucane sesquiterpenes has been developed by use of a novel and key rearrangement of a eudesmane enol ester epoxide. As an example, the 7-epi-14-isocyano-isodauc-5-ene has been successfully synthesized by a series of transformations from α-(-)-santonin.

Original language	English
Pages (from-to)	41-44
Number of pages	4
Journal	Synthesis (Germany)
Issue number	1
State	Published - 2003
Externally published	Yes

Keywords

Epoxides
Eudesmane
Isodaucane
Natural products
Rearrangements
Terpenoids

Cite this

@article{c2ea6d665cec40328888d8505e081302,

title = "A general approach from eudesmane to isodaucane sesquiterpenes: Synthesis of 7-epi-14-isocyano-isodauc-5-ene from α-(-)-santonin",

abstract = "A general and efficient approach for synthesis of an isodaucane sesquiterpenes has been developed by use of a novel and key rearrangement of a eudesmane enol ester epoxide. As an example, the 7-epi-14-isocyano-isodauc-5-ene has been successfully synthesized by a series of transformations from α-(-)-santonin.",

keywords = "Epoxides, Eudesmane, Isodaucane, Natural products, Rearrangements, Terpenoids",

author = "\{Run Li\}, De and \{Jiong Xia\}, Wu and Lei Shi and Tu, \{Yong Qiang\}",

year = "2003",

language = "英语",

pages = "41--44",

journal = "Synthesis (Germany)",

issn = "0039-7881",

publisher = "Georg Thieme Verlag",

number = "1",

}

TY - JOUR

T1 - A general approach from eudesmane to isodaucane sesquiterpenes

T2 - Synthesis of 7-epi-14-isocyano-isodauc-5-ene from α-(-)-santonin

AU - Run Li, De

AU - Jiong Xia, Wu

AU - Shi, Lei

AU - Tu, Yong Qiang

PY - 2003

Y1 - 2003

N2 - A general and efficient approach for synthesis of an isodaucane sesquiterpenes has been developed by use of a novel and key rearrangement of a eudesmane enol ester epoxide. As an example, the 7-epi-14-isocyano-isodauc-5-ene has been successfully synthesized by a series of transformations from α-(-)-santonin.

AB - A general and efficient approach for synthesis of an isodaucane sesquiterpenes has been developed by use of a novel and key rearrangement of a eudesmane enol ester epoxide. As an example, the 7-epi-14-isocyano-isodauc-5-ene has been successfully synthesized by a series of transformations from α-(-)-santonin.

KW - Epoxides

KW - Eudesmane

KW - Isodaucane

KW - Natural products

KW - Rearrangements

KW - Terpenoids

UR - https://www.scopus.com/pages/publications/0037244673

M3 - 文章

AN - SCOPUS:0037244673

SN - 0039-7881

SP - 41

EP - 44

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 1

ER -

A general approach from eudesmane to isodaucane sesquiterpenes: Synthesis of 7-epi-14-isocyano-isodauc-5-ene from α-(-)-santonin

Abstract

Keywords

Other files and links

Fingerprint

Cite this