A comprehensive review on iron‒carbon microelectrolysis constructed wetlands: Efficiency, mechanism and prospects

The traditional constructed wetlands (CWs) face challenges such as significant seasonal fluctuations in decontamination performance and susceptibility to clogging, with the bottlenecks in advanced wastewater treatment becoming increasingly prominent. The iron‒carbon microelectrolysis coupled with constructed wetlands (ICME‒CWs) represents a promising new type of CWs, capable of removing typical and emerging pollutants in water through various mechanisms including adsorption, precipitation, oxidation‒reduction, microelectrolysis, and plant‒microbial synergy. Therefore, this review summarizes the sources, preparation, and basic properties of the ICME substrate commonly used in ICME‒CWs in recent years. It systematically outlines the decontamination mechanisms of ICME‒CWs and their removal performance for pollutants. Additionally, the potential ecological effects of ICME on wetland organisms (microorganisms and plants) are discussed. Finally, the prospects and challenges of ICME‒CWs in applications such as greenhouse gas reduction, groundwater remediation, and the removal of emerging pollutants are proposed. This review aims to advance the development of ICME‒CWs technology for efficient wastewater treatment and provide prospects and guidance for the sustainable and environmentally friendly development of CWs.