A 3D finite deformation constitutive model for anisotropic shape memory polymer composites integrating viscoelasticity and phase transition concept

The phase transition theory of shape memory polymers (SMPs) often involves a phenomenological assumption that the reference configuration of the newly transformed phase deviates from that of the initial phase. This distinction serves as a crucial mechanism in the manifestation of the shape memory effect. However, elucidating the precise definition of the reference configuration of the transformed phase poses a significant challenge in the formulation of the constitutive model. To tackle this challenge, a three-dimensional (3D) finite deformation constitutive model incorporating effective phase evolution for SMPs has been developed. This model merges insights from the classical viscoelastic framework with the phase transition theory. The anisotropic thermo-viscoelastic constitutive model is further developed by introducing hyperelastic fibers, which integrate the anisotropy of the fibers into a continuous thermodynamic framework through structure tensors. Implemented within the ABAQUS software via a user material (UMAT) subroutine, the proposed model has been meticulously validated against experimental data, showcasing its prowess in simulating stress-strain responses and shape memory characteristics of SMPs and their composites (SMPCs). This innovative model stands as an invaluable instrument for the design and of sophisticated SMP and SMPC structures.