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3D energetic metal-organic frameworks: Synthesis and properties of high energy materials

  • Shenghua Li
  • , Yuan Wang
  • , Cai Qi
  • , Xiuxiu Zhao
  • , Jichuan Zhang
  • , Shaowen Zhang
  • , Siping Pang
  • Beijing Institute of Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Energetic 3D MOFs: A structurally unique class of three-dimensional energetic metal-organic frameworks (MOFs) was successfully synthesized and characterized. These MOFs have a good thermal stability and a low sensitivity to impact, friction, and electrostatic discharge. The depicted 3D porous MOF shows the unprecedented heat of detonation of 3.62 kcal g-1.

Original languageEnglish
Pages (from-to)14031-14035
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number52
DOIs
StatePublished - 23 Dec 2013
Externally publishedYes

Keywords

  • energetic materials
  • heats of detonation
  • mesoporous materials
  • metal-organic frameworks
  • nitrogen-rich heterocycles

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