2D and 3D sulfate-water supramolecular networks templated via triazole-nickel(II) complexes

Peng Ren; Bin Ding; Wei Shi; Ying Wang; Tongbu Lu; Peng Cheng

doi:10.1016/j.ica.2006.04.024

2D and 3D sulfate-water supramolecular networks templated via triazole-nickel(II) complexes

Peng Ren
, Bin Ding
, Wei Shi
, Ying Wang
, Tongbu Lu
, Peng Cheng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Tuning the substituents of triazoles, we obtained di- and tri-nuclearic triazole-nickel complexes [Ni₂(deatrz)₄(H₂O)₅](SO₄)₂ · 7H₂O (1) and [Ni₃(dmtrz)₆(H₂O)₆](SO₄)₃ · 21H₂O (2) (deatrz = 3,5-diethanyl-4-amino-1,2,4-triazole; dmtrz = 3,5-dimethanyl-1,2,4-triazole). The X-ray single-crystal diffraction results reveal that sulfate anions and water clusters form supramolecular networks in both complexes. In 1, a supramolecular two-dimensional structure was fabricated by nano-sized grid with novel tetramer water rings templated via binuclear-nickel(II) cations, while in 2, water molecules and sulfate anions construct the first sulfate-water three-dimensional supramolecular network as host to encapsulate trinuclear-nickel guests.

Original language	English
Pages (from-to)	3824-3830
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	359
Issue number	12
DOIs	https://doi.org/10.1016/j.ica.2006.04.024
State	Published - 1 Sep 2006
Externally published	Yes

Keywords

Nickel(II) complex
Supramolecular network
Triazole
Water cluster

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@article{f1c46dfaae144d2ba51ff4326c12c447,

title = "2D and 3D sulfate-water supramolecular networks templated via triazole-nickel(II) complexes",

abstract = "Tuning the substituents of triazoles, we obtained di- and tri-nuclearic triazole-nickel complexes [Ni2(deatrz)4(H2O)5](SO4)2 · 7H2O (1) and [Ni3(dmtrz)6(H2O)6](SO4)3 · 21H2O (2) (deatrz = 3,5-diethanyl-4-amino-1,2,4-triazole; dmtrz = 3,5-dimethanyl-1,2,4-triazole). The X-ray single-crystal diffraction results reveal that sulfate anions and water clusters form supramolecular networks in both complexes. In 1, a supramolecular two-dimensional structure was fabricated by nano-sized grid with novel tetramer water rings templated via binuclear-nickel(II) cations, while in 2, water molecules and sulfate anions construct the first sulfate-water three-dimensional supramolecular network as host to encapsulate trinuclear-nickel guests.",

keywords = "Nickel(II) complex, Supramolecular network, Triazole, Water cluster",

author = "Peng Ren and Bin Ding and Wei Shi and Ying Wang and Tongbu Lu and Peng Cheng",

year = "2006",

month = sep,

day = "1",

doi = "10.1016/j.ica.2006.04.024",

language = "英语",

volume = "359",

pages = "3824--3830",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - 2D and 3D sulfate-water supramolecular networks templated via triazole-nickel(II) complexes

AU - Ren, Peng

AU - Ding, Bin

AU - Shi, Wei

AU - Wang, Ying

AU - Lu, Tongbu

AU - Cheng, Peng

PY - 2006/9/1

Y1 - 2006/9/1

N2 - Tuning the substituents of triazoles, we obtained di- and tri-nuclearic triazole-nickel complexes [Ni2(deatrz)4(H2O)5](SO4)2 · 7H2O (1) and [Ni3(dmtrz)6(H2O)6](SO4)3 · 21H2O (2) (deatrz = 3,5-diethanyl-4-amino-1,2,4-triazole; dmtrz = 3,5-dimethanyl-1,2,4-triazole). The X-ray single-crystal diffraction results reveal that sulfate anions and water clusters form supramolecular networks in both complexes. In 1, a supramolecular two-dimensional structure was fabricated by nano-sized grid with novel tetramer water rings templated via binuclear-nickel(II) cations, while in 2, water molecules and sulfate anions construct the first sulfate-water three-dimensional supramolecular network as host to encapsulate trinuclear-nickel guests.

AB - Tuning the substituents of triazoles, we obtained di- and tri-nuclearic triazole-nickel complexes [Ni2(deatrz)4(H2O)5](SO4)2 · 7H2O (1) and [Ni3(dmtrz)6(H2O)6](SO4)3 · 21H2O (2) (deatrz = 3,5-diethanyl-4-amino-1,2,4-triazole; dmtrz = 3,5-dimethanyl-1,2,4-triazole). The X-ray single-crystal diffraction results reveal that sulfate anions and water clusters form supramolecular networks in both complexes. In 1, a supramolecular two-dimensional structure was fabricated by nano-sized grid with novel tetramer water rings templated via binuclear-nickel(II) cations, while in 2, water molecules and sulfate anions construct the first sulfate-water three-dimensional supramolecular network as host to encapsulate trinuclear-nickel guests.

KW - Nickel(II) complex

KW - Supramolecular network

KW - Triazole

KW - Water cluster

UR - https://www.scopus.com/pages/publications/33746214560

U2 - 10.1016/j.ica.2006.04.024

DO - 10.1016/j.ica.2006.04.024

M3 - 文章

AN - SCOPUS:33746214560

SN - 0020-1693

VL - 359

SP - 3824

EP - 3830

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 12

ER -

2D and 3D sulfate-water supramolecular networks templated via triazole-nickel(II) complexes

Abstract

Keywords

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