2D and 3D networks of lanthanide with mixed dicarboxylate ligands: Syntheses, crystal structures and photoluminescent properties

Qing Feng Yang; Yang Yu; Tian You Song; Jie Hui Yu; Xiao Zhang; Ji Qing Xu; Tie Gang Wang

doi:10.1039/b900522f

2D and 3D networks of lanthanide with mixed dicarboxylate ligands: Syntheses, crystal structures and photoluminescent properties

Qing Feng Yang
, Yang Yu
, Tian You Song
, Jie Hui Yu
, Xiao Zhang
, Ji Qing Xu^*
, Tie Gang Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

College of Chemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

A series of lanthanide complexes with mixed polycarboxylate ligands, [Ln₂(op)₂(ox)(H₂O)₄] _n·nH₂O (Ln = Ce, Pr, Nd, Sm, Eu and Gd for 1-6, respectively), [KLn(pma)_1/2(ox)(H₂O)]_n (Ln = Tb (7) and Dy (8)), [KLn₂(mp)₃(ox)_1/2(H ₂O)₃]_n (Ln = Ce(9) and Pr(10)) (op = o-phthalate, ox = oxalate, pma = pyromellitate and mp = m-phthalate), have been prepared, and their photoluminescent properties have been investigated. Compounds 1-6 show (3,4)-connected 2D network structures consisting of {Ln(op)}_n staircase chains bridged by ox ligands. Compounds 7 and 8 consist of 1D zigzag {Dy(ox)}_n chains linked by pma ligands adopting a new μ₄-hexadentate coordination mode to form 2D 6-connected networks with (3⁶·4⁶·5³) topology. Through K⋯O interactions, the 2D networks are further connected to construct 3D structures. Compounds 9 and 10 display inorganic-organic 3D topology networks with the Schläfli symbol (3·4³· 5²)(3²·4¹⁰·5⁹· 6¹⁴·7)(4²·5) containing mixed (3,4,9)-connected nodes.

Original language	English
Pages (from-to)	1642-1649
Number of pages	8
Journal	CrystEngComm
Volume	11
Issue number	8
DOIs	https://doi.org/10.1039/b900522f
State	Published - 2009

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@article{3c38f707624f4599891b25a70e1edadd,

title = "2D and 3D networks of lanthanide with mixed dicarboxylate ligands: Syntheses, crystal structures and photoluminescent properties",

abstract = "A series of lanthanide complexes with mixed polycarboxylate ligands, [Ln2(op)2(ox)(H2O)4] n·nH2O (Ln = Ce, Pr, Nd, Sm, Eu and Gd for 1-6, respectively), [KLn(pma)1/2(ox)(H2O)]n (Ln = Tb (7) and Dy (8)), [KLn2(mp)3(ox)1/2(H 2O)3]n (Ln = Ce(9) and Pr(10)) (op = o-phthalate, ox = oxalate, pma = pyromellitate and mp = m-phthalate), have been prepared, and their photoluminescent properties have been investigated. Compounds 1-6 show (3,4)-connected 2D network structures consisting of \{Ln(op)\}n staircase chains bridged by ox ligands. Compounds 7 and 8 consist of 1D zigzag \{Dy(ox)\}n chains linked by pma ligands adopting a new μ4-hexadentate coordination mode to form 2D 6-connected networks with (36·46·53) topology. Through K⋯O interactions, the 2D networks are further connected to construct 3D structures. Compounds 9 and 10 display inorganic-organic 3D topology networks with the Schl{\"a}fli symbol (3·43· 52)(32·410·59· 614·7)(42·5) containing mixed (3,4,9)-connected nodes.",

author = "Yang, \{Qing Feng\} and Yang Yu and Song, \{Tian You\} and Yu, \{Jie Hui\} and Xiao Zhang and Xu, \{Ji Qing\} and Wang, \{Tie Gang\}",

year = "2009",

doi = "10.1039/b900522f",

language = "英语",

volume = "11",

pages = "1642--1649",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "8",

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TY - JOUR

T1 - 2D and 3D networks of lanthanide with mixed dicarboxylate ligands

T2 - Syntheses, crystal structures and photoluminescent properties

AU - Yang, Qing Feng

AU - Yu, Yang

AU - Song, Tian You

AU - Yu, Jie Hui

AU - Zhang, Xiao

AU - Xu, Ji Qing

AU - Wang, Tie Gang

PY - 2009

Y1 - 2009

N2 - A series of lanthanide complexes with mixed polycarboxylate ligands, [Ln2(op)2(ox)(H2O)4] n·nH2O (Ln = Ce, Pr, Nd, Sm, Eu and Gd for 1-6, respectively), [KLn(pma)1/2(ox)(H2O)]n (Ln = Tb (7) and Dy (8)), [KLn2(mp)3(ox)1/2(H 2O)3]n (Ln = Ce(9) and Pr(10)) (op = o-phthalate, ox = oxalate, pma = pyromellitate and mp = m-phthalate), have been prepared, and their photoluminescent properties have been investigated. Compounds 1-6 show (3,4)-connected 2D network structures consisting of {Ln(op)}n staircase chains bridged by ox ligands. Compounds 7 and 8 consist of 1D zigzag {Dy(ox)}n chains linked by pma ligands adopting a new μ4-hexadentate coordination mode to form 2D 6-connected networks with (36·46·53) topology. Through K⋯O interactions, the 2D networks are further connected to construct 3D structures. Compounds 9 and 10 display inorganic-organic 3D topology networks with the Schläfli symbol (3·43· 52)(32·410·59· 614·7)(42·5) containing mixed (3,4,9)-connected nodes.

AB - A series of lanthanide complexes with mixed polycarboxylate ligands, [Ln2(op)2(ox)(H2O)4] n·nH2O (Ln = Ce, Pr, Nd, Sm, Eu and Gd for 1-6, respectively), [KLn(pma)1/2(ox)(H2O)]n (Ln = Tb (7) and Dy (8)), [KLn2(mp)3(ox)1/2(H 2O)3]n (Ln = Ce(9) and Pr(10)) (op = o-phthalate, ox = oxalate, pma = pyromellitate and mp = m-phthalate), have been prepared, and their photoluminescent properties have been investigated. Compounds 1-6 show (3,4)-connected 2D network structures consisting of {Ln(op)}n staircase chains bridged by ox ligands. Compounds 7 and 8 consist of 1D zigzag {Dy(ox)}n chains linked by pma ligands adopting a new μ4-hexadentate coordination mode to form 2D 6-connected networks with (36·46·53) topology. Through K⋯O interactions, the 2D networks are further connected to construct 3D structures. Compounds 9 and 10 display inorganic-organic 3D topology networks with the Schläfli symbol (3·43· 52)(32·410·59· 614·7)(42·5) containing mixed (3,4,9)-connected nodes.

UR - https://www.scopus.com/pages/publications/69249124485

U2 - 10.1039/b900522f

DO - 10.1039/b900522f

M3 - 文章

AN - SCOPUS:69249124485

SN - 1466-8033

VL - 11

SP - 1642

EP - 1649

JO - CrystEngComm

JF - CrystEngComm

IS - 8

ER -

2D and 3D networks of lanthanide with mixed dicarboxylate ligands: Syntheses, crystal structures and photoluminescent properties

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