介孔骨架包裹纳米碳酸钙循环吸收CO2性能研究

Siyu Wei; Rui Han; Yanlin Su; Jihui Gao

doi:10.11715/rskxjs.R201705030

介孔骨架包裹纳米碳酸钙循环吸收CO₂性能研究

Translated title of the contribution: CO₂ Sorption Enhancement of Nano Calcium Carbonate Wrapped with the Mesoporous Skeleton

Siyu Wei
, Rui Han
, Yanlin Su
, Jihui Gao^*

^*Corresponding author for this work

School of Energy Science and Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The nano calcium carbonate sorbent wrapped with the mesoporous SiO₂ skeleton for CO₂ capture performance was prepared by sol-gel method and the sorbent performance in cyclic calcination/carbonation was studied by TGA.The uptake of CO₂ in the first and the 15th cycle of composite sorbent was 13.4,mol/kg and 6.1,mol/kg,increased by 32%, and 41%,respectively,compared with untreated nano calcium carbonate.The average pore size of porous skeleton decreased with the addition of TMB and the capacity of the sorbent then decreased.A number of nano CaCO₃ are coated in the SiO₂ framework,where mesopores allow the transfer of reactant gas into fresh sorbent particles.The skeleton also inhibits the agglomeration of the nano CaCO₃ because of sintering and improves the activity of the sorbent.

Translated title of the contribution	CO₂ Sorption Enhancement of Nano Calcium Carbonate Wrapped with the Mesoporous Skeleton
Original language	Chinese (Traditional)
Pages (from-to)	132-138
Number of pages	7
Journal	Ranshao Kexue Yu Jishu/Journal of Combustion Science and Technology
Volume	24
Issue number	2
DOIs	https://doi.org/10.11715/rskxjs.R201705030
State	Published - 15 Apr 2018
Externally published	Yes

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title = "介孔骨架包裹纳米碳酸钙循环吸收CO2性能研究",

abstract = "The nano calcium carbonate sorbent wrapped with the mesoporous SiO2 skeleton for CO2 capture performance was prepared by sol-gel method and the sorbent performance in cyclic calcination/carbonation was studied by TGA.The uptake of CO2 in the first and the 15th cycle of composite sorbent was 13.4,mol/kg and 6.1,mol/kg,increased by 32\%, and 41\%,respectively,compared with untreated nano calcium carbonate.The average pore size of porous skeleton decreased with the addition of TMB and the capacity of the sorbent then decreased.A number of nano CaCO3 are coated in the SiO2 framework,where mesopores allow the transfer of reactant gas into fresh sorbent particles.The skeleton also inhibits the agglomeration of the nano CaCO3 because of sintering and improves the activity of the sorbent.",

keywords = "CO capture, Calcium-based sorbent, Mesoporous skeleton, Sol-gel",

author = "Siyu Wei and Rui Han and Yanlin Su and Jihui Gao",

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doi = "10.11715/rskxjs.R201705030",

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T1 - 介孔骨架包裹纳米碳酸钙循环吸收CO2性能研究

AU - Wei, Siyu

AU - Han, Rui

AU - Su, Yanlin

AU - Gao, Jihui

PY - 2018/4/15

Y1 - 2018/4/15

N2 - The nano calcium carbonate sorbent wrapped with the mesoporous SiO2 skeleton for CO2 capture performance was prepared by sol-gel method and the sorbent performance in cyclic calcination/carbonation was studied by TGA.The uptake of CO2 in the first and the 15th cycle of composite sorbent was 13.4,mol/kg and 6.1,mol/kg,increased by 32%, and 41%,respectively,compared with untreated nano calcium carbonate.The average pore size of porous skeleton decreased with the addition of TMB and the capacity of the sorbent then decreased.A number of nano CaCO3 are coated in the SiO2 framework,where mesopores allow the transfer of reactant gas into fresh sorbent particles.The skeleton also inhibits the agglomeration of the nano CaCO3 because of sintering and improves the activity of the sorbent.

AB - The nano calcium carbonate sorbent wrapped with the mesoporous SiO2 skeleton for CO2 capture performance was prepared by sol-gel method and the sorbent performance in cyclic calcination/carbonation was studied by TGA.The uptake of CO2 in the first and the 15th cycle of composite sorbent was 13.4,mol/kg and 6.1,mol/kg,increased by 32%, and 41%,respectively,compared with untreated nano calcium carbonate.The average pore size of porous skeleton decreased with the addition of TMB and the capacity of the sorbent then decreased.A number of nano CaCO3 are coated in the SiO2 framework,where mesopores allow the transfer of reactant gas into fresh sorbent particles.The skeleton also inhibits the agglomeration of the nano CaCO3 because of sintering and improves the activity of the sorbent.

KW - CO capture

KW - Calcium-based sorbent

KW - Mesoporous skeleton

KW - Sol-gel

UR - https://www.scopus.com/pages/publications/85061200125

U2 - 10.11715/rskxjs.R201705030

DO - 10.11715/rskxjs.R201705030

M3 - 文章

AN - SCOPUS:85061200125

SN - 1006-8740

VL - 24

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EP - 138

JO - Ranshao Kexue Yu Jishu/Journal of Combustion Science and Technology

JF - Ranshao Kexue Yu Jishu/Journal of Combustion Science and Technology

IS - 2

ER -

介孔骨架包裹纳米碳酸钙循环吸收CO₂性能研究

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